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Determination of the crystal structure of CuSnTi by full profile Rietveld analysis

Published online by Cambridge University Press:  10 January 2013

F. Weitzer ,
L. Perring ,
T. Shibayanagi ,
M. Naka  and
J. C. Schuster
F. Weitzer
Affiliation:
Institut für Physikalische Chemie, Universität Wien, Vienna, Austria
L. Perring
Affiliation:
Institut de Chimie Minérale et Analytique, Université de Lausanne, Switzerland
T. Shibayanagi
Affiliation:
Joining and Welding Research Institute, Osaka University, Osaka, Japan
M. Naka
Affiliation:
Joining and Welding Research Institute, Osaka University, Osaka, Japan
J. C. Schuster
Affiliation:
Institut für Physikalische Chemie, Universität Wien, Vienna, Austria
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Abstract

The crystal structure of the new ternary phase CuSnTi is determined by full profile Rietveld analysis of the powder diffractogram. 104 reflections were refined to a final RBragg value of 5.60%. CuSnTi crystallizes with the spacegroup P63/mmc and is isostructural to InNi2. The lattice parameters are a=0.439 555(5) nm and c=0.601 505(9) nm.

Type
Technical Articles
Information
Powder Diffraction , Volume 15 , Issue 2 , June 2000 , pp. 91 - 93
Copyright
Copyright © Cambridge University Press 2000

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References

Brandon, J. K., Pearson, W. B., and Tozer, D. J. H. (1975). “A single crystal x-ray study of the ζ bronze structure, Cu 20Sn 6,”Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B31, 774–779.CrossRefGoogle Scholar
Gangulee, A., Das, G. C., and Bever, M. B. (1973). “An x-ray diffraction and calorimetric investigation of the compound Cu 6Sn 5,”Metal. Trans. 4, 2063–2066.CrossRefGoogle Scholar
Lenz, J., and Schubert, K. (1971). “Crystal structure of Cu 10Sn 3 (m),” Monatsh. Chem. 102, 1689–1698.CrossRefGoogle Scholar
Naka, M., Shibayanagi, T., and Schuster, J. C. (1999). “Phase equilibria in the system Cu–Sn–Ti” (unpublished).Google Scholar
Rietveld, H. M. (1969). “A profile refinement method for nuclear and magnetic structures,” J. Appl. Crystallogr. 2, 65–71.CrossRefGoogle Scholar
Rodriguez-Carjaval, J. (1997). Computer program “FullProf,” version 3.3, Aug. 97-LLB-JRC (Laboratoire Leon Brillouin, CEA-CNRS, Grenoble, France).Google Scholar
Schuster, J. C., Naka, M., and Shibayanagi, T. (1999). “Crystal structure of the phase CuSn 3Ti 5” (unpublished).Google Scholar
Urai, S., Kimura, H., Maeda, K., and Naka, M. (1998). “Brazing of SiC using CuSnTi alloys,” DVS Ber. 192, 314–316.Google Scholar
Villars, P., and Calvert, L. D. (1991) Pearsons Handbook of Crystallographic Data for Intermetallic Phases (ASM, Materials Park, OH).Google Scholar