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The Crystal Structures and Powder Diffraction Patterns of the Bismuth and Thallium Ruddlesden-Popper Copper Oxide Superconductors

Published online by Cambridge University Press:  10 January 2013

David. P. Matheis  and
Robert L. Snyder
David. P. Matheis
Affiliation:
Institute far Ceramic Superconductivity, New York State College of Ceramics atAlfred University, Alfred, New York 14802, U.S.A.
Robert L. Snyder
Affiliation:
Institute far Ceramic Superconductivity, New York State College of Ceramics atAlfred University, Alfred, New York 14802, U.S.A.
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Abstract

This paper contains a review and explanation of the super conducting Ruddlesden-Popper phases in the systems Bi-Sr-Ca-Cu-O and Tl-Ba-Ca-Cu-O. Calculated powder X-ray patterns for the phases Bi-2201, 2212, 2223, and 2234 (where the numbers refer to the stoichiometric ratios of Bi:Sr:Ca:Cu) and Tl-1201, 1212, 1223, 1234, 2201, 2212, 2223, and 2234 (here the numbers refer to the molar ratios of Bi:Ba:Ca:Cu) generated from the reviewed crystal structures are presented. Observed powder patterns for Tl-2201, Tl-2212, Bi-2201 and Bi-2212 are included and compared to the calculated patterns of these phases.

Type
Research Article
Information
Powder Diffraction , Volume 5 , Issue 1 , March 1990 , pp. 8 - 25
Copyright
Copyright © Cambridge University Press1990

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