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Crystal structure of Ca2Zn2(V4O14) and Pb2Cd2(V3O10)(VO4) double vanadates

Published online by Cambridge University Press:  14 June 2018

V. D. Zhuravlev Open the ORCID record for V. D. Zhuravlev [Opens in a new window] ,
A. P. Tyutyunnik ,
A. Y. Chufarov ,
N. I. Lobachevskaya  and
A. A. Velikodnyi
V. D. Zhuravlev*
Affiliation:
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya ul. 91, Ekaterinburg 620990, Russia
A. P. Tyutyunnik
Affiliation:
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya ul. 91, Ekaterinburg 620990, Russia
A. Y. Chufarov
Affiliation:
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya ul. 91, Ekaterinburg 620990, Russia
N. I. Lobachevskaya
Affiliation:
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya ul. 91, Ekaterinburg 620990, Russia
A. A. Velikodnyi
Affiliation:
Faculty of Chemistry, Moscow State University, Moscow 119992, Russia
*
a)Author to whom correspondence should be addressed. Electronic mail: [email protected]
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Abstract

Polycrystalline samples of Ca2Zn2(V4O14) (I) and Pb2Cd2(V3O10)(VO4) (II) were synthesized using the nitrate–citrate method (I) and conventional solid state reaction (II). The structural refinement based on X-ray powder diffraction data showed that the crystal structure of (I) is characterized by monoclinic symmetry with unit-cell parameters a = 6.8044(1) Å, b = 14.4876(3) Å, c = 11.2367(2) Å, β = 99.647(1)° [space group P21/c (No. 14), Z = 4], and the crystal structure of (II) is triclinic with unit-cell parameters a = 7.03813(6) Å, b = 12.9085(1) Å, c = 6.99961(5) Å, α = 90.7265(5)°, β = 96.3789(5)°, γ = 94.9530(6)°, V = 629.470(8) Å3 [space group P$\bar 1$ (No. 2), Z = 2].

Keywords

double vanadatesX-ray powder diffractioncrystal structure
Type
New Diffraction Data
Information
Powder Diffraction , Volume 33 , Issue 3 , September 2018 , pp. 216 - 224
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Copyright
Copyright © International Centre for Diffraction Data 2018 

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