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Crystal Data for LnKFe (CN)6·4H20, Ln=La, Ce, Pr, and Nd Compound

Published online by Cambridge University Press:  10 January 2013

D.F. Mullica  and
E.L. Sappenfield
D.F. Mullica
Affiliation:
Departments of Chemistry and Physics, Baylor University, Waco, Texas 76798, U.S.A.
E.L. Sappenfield
Affiliation:
Departments of Chemistry and Physics, Baylor University, Waco, Texas 76798, U.S.A.
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Abstract

Crystal data and a representative X-ray powder diffraction pattern are reported for a series of isomorphous compounds, LnKFe(CN)6.4H2O where Ln = La, Ce, Pr and Nd. They crystallize in the hexagonal space group P63/m (176) with Z = 2. A plot of the unit cell volume (V) versus the cube of the Ln ionic radius (r3) yields linearity with a correlation coeficient of 0.9998.

Type
Research Article
Information
Powder Diffraction , Volume 4 , Issue 2 , June 1989 , pp. 101 - 102
Copyright
Copyright © Cambridge University Press 1989

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References

Beall, G.W., Mullica, D.F., Milligan, W.O., Korp, J., & Bernal, I. (1978). Ada Crystallogr., B34, 1446–1449.CrossRefGoogle Scholar
Cotton, F.A. and Wilkinson, G. (1980). Advanced Inorganic Chemistry, 4th Ed., pp. 981–983. New York: J. Wiley and Sons.Google Scholar
Milligan, W.O., Mullica, D.F., & Perkins, H.O. (1982). Inorg. Chem. Acta 60, 35–38.CrossRefGoogle Scholar
Mullica, D.F., Milligan, W.O., & Oliver, J.D. (1979). Inorg. Nucl. Chem. Lett. 15, 1–5.CrossRefGoogle Scholar
Muljica, D.F., Sappenfield, E.L., & Perkins, H.O. (1988). J. Solid State Chem. 73, 65–70.CrossRefGoogle Scholar
Prandtl, W. & Mohr, S. (1938). Z. Anorg. Allg. Chem. 236, 243–251.CrossRefGoogle Scholar
Roof, R.B. Jr., (Personal Communication)Google Scholar
Shannon, R.D. (1976). Acta Crystallogr. A32, 751–767.CrossRefGoogle Scholar
Smith, G.S., & Snyder, R.L. (1979). J. Appl. Crystallogr. 23, 60–65.CrossRefGoogle Scholar
de Wolff, P.M. (1968). J. Appl. Crystallogr. 1, 108–113.CrossRefGoogle Scholar