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Chemical preparation and crystal data for two condensed phosphates NiCs4(PO3)6 and NiK4(P3O9)2

Published online by Cambridge University Press:  05 March 2012

Kacem Sbai ,
Said Belaaouad ,
Abdelkebir Kenz ,
El Mostafa Tace  and
Malika Tridane
Kacem Sbai
Affiliation:
Laboratoire de Recherches de Chimie-Physique Ge´ne´rale, Faculte´ des Sciences Ben M’Sik, BP 7955, Casablanca. Morocco
Said Belaaouad*
Affiliation:
Laboratoire de Recherches de Chimie-Physique Ge´ne´rale, Faculte´ des Sciences Ben M’Sik, BP 7955, Casablanca. Morocco
Abdelkebir Kenz
Affiliation:
Laboratoire de Recherches de Chimie-Physique Ge´ne´rale, Faculte´ des Sciences Ben M’Sik, BP 7955, Casablanca. Morocco
El Mostafa Tace
Affiliation:
Laboratoire de Recherches de Chimie-Physique Ge´ne´rale, Faculte´ des Sciences Ben M’Sik, BP 7955, Casablanca. Morocco
Malika Tridane
Affiliation:
Laboratoire de Recherches de Chimie-Physique Ge´ne´rale, Faculte´ des Sciences Ben M’Sik, BP 7955, Casablanca. Morocco
*
a)Electronic mail: [email protected]
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Abstract

Methods of chemical preparation and crystallographic data are reported for two new condensed phosphates: a polyphosphate of nickel and cesium, NiCs4(PO3)6, and a cyclotriphosphate of nickel and potassium, NiK4(P3O9)2. NiCs4(PO3)6 is rhombohedral with the following unit-cell dimensions: a=b=11.602(1) Å, c=9.078(1) Å, space group P−31c, V=1058.24(1) Å3, and Z=2. NiK4(P3O9)2 is triclinic with the following unit-cell dimensions: a=6.143(8) Å, b=6.80(1) Å, c=12.80(3) Å, α=102.8(3)°, β=89.7(2)°, γ=66.03(7)°, space group P−1, V=473.56(3) Å3, and Z=1.

Type
New Diffraction Data
Information
Powder Diffraction , Volume 19 , Issue 4 , December 2004 , pp. 375 - 377
Copyright
Copyright © Cambridge University Press 2004

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References

Abouimrane, A. (2000). “Etude thermique et vibrationnelle des cyclotriphosphates hydrate´s a` cycles de syme´trie CsMIIK4(P3O9)2.7H2O (MII=Ni,Co) et ZnM4I(P3O9)2.6H2O (MI=K,Rb). Elaboration et caracte´risation structurale d’un nouveau monophosphate a` cation organique (NH3C6H4COOH)2(H2PO4)2.2H2O,” the`se Universite´ Hassan II—Mohamme´dia, Faculte´ des Sciences Ben M’sik Casablanca. Maroc.Google Scholar
Averbuch-Pouchot, M. T. and Durif, A. (1986). “Structure of monobarium and tetra-cesium polyphosphate,” Acta Crystallogr., Sect. C: Cryst. Struct. Commun. ACSCEE C42 928–950. acg ACSCEE CrossRefGoogle Scholar
Boulle´, A. (1938). “Pre´paration du cyclophosphate d’argent monohydrate´,” C. R. Acad. Sci. ZZZZZZ 206 517–518.Google Scholar
Durif, A.Grenier, J. C.Pouchot, M. T., and Tranqui, D. (1966). “Forme rhomboe´drique des me´taphosphates de type MIIK(PO3)3 avec MII=Co, Ni, Mg, Zn,” Bull. Soc. Fr. Mineral. Cristallogr. BUFCAE 89 273–274. buf BUFCAE Google Scholar
Evain, M., (1992). “U-FIT: A cell parameter refinement program,” IMN, Nantes, France.Google Scholar
Jost, K. H. and Schulze, J. (1971). “Mechanismen der phasentransformationen des KPO3 und die struktur der Ho¨chst-temperatur-modifikation des KPO3,” Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. ACBCAR B25 1110–1112. acb ACBCAR Google Scholar
Jouini, A. and Dabbabi, M. (1985). “Pre´parations chimiques et donne´es cristallographiques sur quatre nouveaux tricyclotriphosphates de nickel et de cations monovalents NiM4I(P3O9)2.xH2O (MI=Na,Ag,NH4,Cs),” C. R. Acad. Sci., Ser. II: Mec., Phys., Chim., Sci. Terre Univers CRAMED 301 1347–1350. csu CRAMED Google Scholar
Jouini, A. and Durif, A. (1983). “Utilisation des re´sines pour la pre´paration des cyclotriphosphates,” C. R. Acad. Sci., Ser. II: Mec., Phys., Chim., Sci. Terre Univers CRAMED 297 573–575. csu CRAMED Google Scholar
Loue¨r, D. and Loue¨r, M. (1972). “Automatic indexation of X-ray diffractograms by the program treor,” J. Appl. Crystallogr. JACGAR 5 271–275. acr JACGAR Google Scholar
Loue¨r, D. and Vargas, R. (1982). “Refinement program treor,” J. Appl. Crystallogr. JACGAR 15 542–545. acr JACGAR Google Scholar
Masse, R. and Averbuch-Pouchot, M. T. (1977). “Diagramme d’e´quilibre du syste`me binaire Ba(PO3)-Cs(PO3); donne´es cristallographiques sur BaCs4(PO3)6, Ba2Cs(PO3)5 et BaCsP3O9.H2O,” Mater. Res. Bull. MRBUAC 12 13–16. mrb MRBUAC CrossRefGoogle Scholar
Matsukizono, H.Nariai, H.Maki, H., and Motooka, I. (1996). “Syntheses and thermal behaviors of some cation-mixed cyclotriphosphates,” Phosphorus Res. Bull. ZZZZZZ 6 269–272.CrossRefGoogle Scholar
Pontchara, P. and Durif, A. (1974). “Etude des diagrammes d’e´quilibre Ni(PO3)2-LiPO3 et Ni(PO3)2-KPO3,” C. R. Acad. Sci. ZZZZZZ C278 175–178.Google Scholar
Sbai, K.Atibi, A.Radid, M., and Jouini, A. (2001). “Etudes des spectres vibrationnels et des proprie´te´s physico-chimiques du cyclotriphosphate mixte de nickel et de sodium hexahydrate´ NiNa4(P3O9)2.6H2O,” Ann. Chim. Sci. Mat. ZZZZZZ 6 45–61.CrossRefGoogle Scholar
Sbai, K.Atibi, A.Belaaouad, S., and Moutaabbid, M. (2002a). “Etude des proprie´te´s physico-chimiques du cyclotriphosphate mixte de nickel et d’argent hexahydrate´, NiAg4(P3O9)2.6H2O,” Phosphorus, Sulfur Silicon Relat. Elem. PSSLEC 177 2345–2362. psq PSSLEC CrossRefGoogle Scholar
Sbai, K.Abouimrane, A.Lahmidi, A.El Kababi, K.Hliwa, M., and Vilminot, S. (2000). “Thermal behavior and vibration studies of NiRb4(P3O9)2.6H2O,” Ann. Chim. Sci. Mater. ZZZZZZ 25 sup 1 S139–S145.Google Scholar
Sbai, K.Abouimrane, A.El Kababi, K., and Vilminot, S. (2002b). “De´gradation thermique et e´tude vibrationnelle de MII(NH4)4(P3O9)2.4H2O (MII=Cu2+,Ni2+,Co2+),” J. Therm Anal. Calorim. JTACF7 68 109–122. aoy JTACF7 CrossRefGoogle Scholar
Seethanen, D.Tordjman, I., and Averbuch-Pouchot, M. T. (1978). “Structure cristalline du trime´taphosphate mixte de nickel-potassium heptahydrate´: NiK4(P3O9)2.7H2O et donne´es cristallographiques de CoK4(P3O9)2.7H2O,” Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. ASBSDK B54 2587–2590. acl ASBSDK Google Scholar