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Cerium Oxygen Apatite (Ce4.67[SiO4]3O) X-Ray Diffraction Pattern Revisited

Published online by Cambridge University Press:  10 January 2013

A. Cuneyt Tas
Affiliation:
Department of Materials Science and Engineering, Iowa State University, Ames, Iowa 50011, U.S.A.
Mufit Akinc
Affiliation:
Department of Materials Science and Engineering, Iowa State University, Ames, Iowa 50011, U.S.A.

Abstract

A new X-ray diffraction pattern for the compound cerium oxygen apatite, Ce4.67[SiO4]3O is suggested. The compound was prepared by the solid state reaction of the oxides, CeO2 and SiO2 and has a hexagonal crystal structure with the lattice constants a = 9.6578 Å and c = 7.1187 Å. The sample of the most recent PDF pattern 31-0336* (Visser, 1978) for this compound is believed to be contaminated with significant quantities of N owing to the fact that it was prepared by mixing Ce2O3 and Si3N4 and its very close resemblance to the pattern displayed in the PDF 33-0333 given for the cerium “nitrogen” apatite, Ce5[SiO4]3N.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1992

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References

Appleman, D.E. & Evans, H.T. (1973). U.S. Geological Survey, Computer Contribution 20, U.S. National Technical Information Service, Document PB-216188.Google Scholar
Belokoneva, E.L., Petrova, T.L., Simonov, M.A. & Belov, N.V. (1972). Soviet Physics-Crystallography 17, 429431.Google Scholar
Felsche, J. (1969). Naturwissenschaften, 22, 325326.CrossRefGoogle Scholar
Gaude, J. (1987). Revue de Chimie Minerale, 24, 2227.Google Scholar
Gaude, J., L'Haridon, P., Hamon, C., Marchand, R. & Laurent, Y. (1975). Bull. Soc. fr. Mineral. Cristallogr. 98, 214217.Google Scholar
Guha, J.P. (1980). J. Mater. Sci. 15, 521522.CrossRefGoogle Scholar
Lange, F.F. & Davis, B.I. (1979). J. Amer. Ceram. Soc. 62, 629630.CrossRefGoogle Scholar
Lange, F.F. (1980). Amer. Ceram. Soc. Bull. 59, 239–240, 249.Google Scholar
Mah, T. et al. , Air Force Materials Laboratory, Wright-Patterson Air Force Base, Ohio, USA, JCPDS File #31-0336.Google Scholar
Mah, T., Mazdiyasni, K.S. & Ruh, R. (1979). J. Amer. Ceram. Soc. 62, 1216.CrossRefGoogle Scholar
Visser, J. (1978). JCPDS Grant-in-Aid Report, JCPDS File Card #31-0336, Technisch Physische Dienst, Delft, Netherlands.Google Scholar