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X-Ray Diffraction and EXAFS Study of Palladium Tetrammine Dichromate, [Pd(NH3)4]Cr2O7

Published online by Cambridge University Press:  10 January 2013

A. Borgna ,
B. Moraweck  and
P. Fessler
A. Borgna
Affiliation:
Institui de Reeherches sur la Catalyse, 2 Avenue Albert Einstein, F 69626 Villeurbanne Cedex & L.U.R.E. Bâtiment 209, Université Paris-Sud, F 91405 Orsay Cedex, France
B. Moraweck*
Affiliation:
Institui de Reeherches sur la Catalyse, 2 Avenue Albert Einstein, F 69626 Villeurbanne Cedex & L.U.R.E. Bâtiment 209, Université Paris-Sud, F 91405 Orsay Cedex, France
P. Fessler
Affiliation:
Institui de Reeherches sur la Catalyse, 2 Avenue Albert Einstein, F 69626 Villeurbanne Cedex & L.U.R.E. Bâtiment 209, Université Paris-Sud, F 91405 Orsay Cedex, France
*
+To whom correspondence should be addressed.
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Abstract

Palladium tetrammine dichromate, [Pd(NH3)4]Cr2O7, was obtained by precipitation from [Pd(NH3)4]Cl2·H2O and (NH4)2Cr2O7. The X-ray diffraction pattern of this compound corresponds to a new phase, which was indexed in the triclinic system, but on a cell that should be considered as preliminary. From the chemical analysis and the X-ray absorption experiments at both K-edges of Pd and Cr, we conclude that the surrounding of these atoms is kept during formation.

Type
Research Article
Information
Powder Diffraction , Volume 4 , Issue 4 , December 1989 , pp. 217 - 219
Copyright
Copyright © Cambridge University Press 1989

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