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X-Ray Diffraction Analysis of Barium-Strontium Sulfate (Barite-Celestite) Solid Solutions

Published online by Cambridge University Press:  10 January 2013

Elihu Goldish
Affiliation:
Dept. of Geological Sciences, California State University, Long Beach, Long Beach, California 90840, U.S.A.

Abstract

Crystal data are given for synthetic mixed bariumstrontium sulfates, and a powder pattern for (Ba0.50Sr0.50)SO4 is presented. Taken with previously published data for the end-member sulfates, we verify the nonlinear behavior of the unit-cell edges with composition, and present tables of interpolated data from which d-spacings for intermediate compositions can be calculated. The use of these data for analysis of complex natural samples by use of the 121 peak is described.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1989

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References

Blount, C.W. (1974). Synthesis of barite, celestite, anglesite, witherite, and strontianite from aqueous solutions. Am. Mineral. 59, 12091219.Google Scholar
Boström, K., Frazer, J. & Blankenburg, J. (1967). Subsolidus phase relations and lattice constants in the system BaSO4-SrSO4-PbSO4. Ark. Mineral. Geol. 4, 477485.Google Scholar
Brower, E. (1973). Synthesis of barite, celestite, and bariumstrontium sulfate solid solution crystals. Geochim. Cosmochim. Acta 37, 155158.CrossRefGoogle Scholar
Burkhard, A. (1973). Optical and X-ray investigations in the system BaSO4-SrSO4. Schweiz. Mineral. Petrogr. Mitt. 53, 185197.Google Scholar
Deer, W.A., Howie, J. & Zussman, J. (1966). An Introduction to the Rock Forming Minerals, pp. 462464. London: Longmans, Green.Google Scholar
Hanor, J.S. (1968). Frequency distribution of compositions in the barite-celestite series. Am. Mineral. 53, 12151222.Google Scholar
International Tables for X-ray Crystallography (1959). Vol. II, p. 108. Birmingham: Kynoch Press.Google Scholar
Renault, J. & Brower, E. (1971). X-ray line broadening in the barium sulfate-strontium sulfate series. Am. Mineral. 56, 14811485.Google Scholar
Sabine, P.A. & Young, P.R. (1954). Cell size and composition of the baryte-celestine isomorphous series. Acta Crystallogr. 7, 630.Google Scholar
Swanson, H.E. & Fuyat, R.K. (1953). Standard X-Ray Diffraction Powder Patterns. Natl. Bur. Stand. (U.S.) Circ. 539, vol. 2, pp. 6162. Washington. D.C.: U.S. Government Printing Office.Google Scholar
Swanson, H.E., McMurdie, H.F., Morris, M.C., Evans, E.H., Paretzkin, B. & Groot, J.H. de (1972). Standard X-Ray Diffraction Powder Patterns. Natl. Bur. Stand. (U.S.) Monogr. 25(10), 1213. Washington, D.C.: U.S. Government Printing Office.CrossRefGoogle Scholar
West, A.R. (1984). Solid State Chemistry and its Applications, pp. 366369. Chichester: Wiley.Google Scholar