Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-30T20:11:02.288Z Has data issue: false hasContentIssue false

Powder diffraction data of semimagnetic semiconductors Hg0.80Mn0.20S, Hg0.89Fe0.11S and Hg0.98Co0.02S

Published online by Cambridge University Press:  10 January 2013

W. Paszkowicz*
Affiliation:
Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warsaw, Poland
*
a)e-mail address: [email protected]

Abstract

Powder X-ray diffraction data are reported for semimagnetic semiconductor Hg0.89Fe0.11S and Hg0.98Co0.02S crystals grown by the Bridgman method and for Hg0.80Mn0.20S crystal synthesized by a solid-state reaction method. The crystals have the sphalerite structure of metacinnabar (sphalerite-type high-temperature polymorph of HgS, space group F4¯3m). Phase analysis does not show any trace of other phases. The lattice parameters of the studied samples are a=5.803 20(5) Å, 5.8063(1) Å and 5.839 80(6) Å, respectively. The calculated density is reported.

Type
New Diffraction Data
Copyright
Copyright © Cambridge University Press 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bernard, J.H., Rost, R., Bernardová, E., Breiter, K., Kašpar, P., Lang, M., Melka, K., Novák, F., Rost, J., Řidkošil, T., Slivka, D., Ulrych, J., and Vrana, S. (1992). Encyklopedicky prehled mineralů (Encyclopedic Survey of Minerals) (Academia, Praha), p. 466 (in Czech).Google Scholar
Curtis, O.L. Jr. (1962). “Effect of a phase transformation on the vapor phase growth of single-crystal HgS,” J. Appl. Phys. 33, 24612463.CrossRefGoogle Scholar
Iwanowski, R.J., Lawniczak-Jablonska, K., Golacki, Z., and Traverse, A. (1998). “Tetrahedral covalent radii of Mn, Fe, Co and Ni estimated from extended X-ray absorption fine structure studies,” Chem. Phys. Lett. 283, 313318.CrossRefGoogle Scholar
Pajaczkowska, A., and Rabenau, A. (1977). “Phase studies and hydrothermal syntheses in the system mercury sulfide-manganese sulfide,” J. Solid State Chem. 21, 4348.CrossRefGoogle Scholar
Paszkowicz, W., Szuszkiewicz, W., Dynowska, E., Domagala, J., Witkowska, B., Marczak, M., and Zinn, P. (1999a). “High pressure-high temperature study of Hg 1−xMn xS,J. Alloys Compd. 286, 208212.CrossRefGoogle Scholar
Paszkowicz, W., Szuszkiewicz, W., Szamota-Sadowska, K., Domagala, J. Z., Witkowska, B., Marczak, M., and Zinn, P. (1999b). “X-ray diffraction study of sphalerite-cinnabar phase transition in Hg 0.985Co 0.015S,Mater. Struct. Chem. Biol. Phys. Technol. 8, 102-103.Google Scholar
Powder Diffraction File (1999). International Centre for Diffraction Data, 12 Campus Boulevard, Newtown Square, PA, 19073-3273.Google Scholar
Szuszkiewicz, W., Dybko, K., Dynowska, E., Witkowska, B., Jouanne, M., and Julien, C. (1995). “Local modes of transition metal ions (Mn, Fe, Co) in mercury chalcogenides,” Acta Phys. Pol. A 88, 937941.CrossRefGoogle Scholar
Szuszkiewicz, W., Dybko, K., Dynowska, E., Witkowska, B., Jouanne, M., and Julien, C. (1998a). “Local modes of transition metal ions (Mn, Fe, Co) in narrow-gap II-VI semiconductors,” Mater. Sci. Eng., B 55, 14.CrossRefGoogle Scholar
Szuszkiewicz, W., Skierbiszewski, C., Paszkowicz, W., Dybko, K., Domagala, J., Dynowska, E., Witkowska, B., and Zinn, P. (1998). “Properties of Fe doped β-HgS under hydrostatic pressure,” Acta Phys. Pol. A 94, 570574.CrossRefGoogle Scholar
Yoder-Short, D.R., Debska, U., and Furdyna, J.K. (1985). “Lattice parameters of Zn 1−xMn xSe and tetrahedral bond length in A 1−xIIMn xB VI alloys,” J. Appl. Phys. 58, 40564060.CrossRefGoogle Scholar