Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-24T17:08:02.362Z Has data issue: false hasContentIssue false
  • English
  • Français

Mechanochemical synthesis of two-dimensional metal-organic frameworks

Published online by Cambridge University Press:  11 April 2019

Omar Barreda ,
Gregory R. Lorzing  and
Eric D. Bloch
Omar Barreda
Affiliation:
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716
Gregory R. Lorzing
Affiliation:
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716
Eric D. Bloch*
Affiliation:
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716
*
a)Author to whom correspondence should be addressed. Electronic mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Powder X-ray diffraction was used to monitor the solvent-free synthesis of two-dimensional (2D) metal–organic frameworks (MOFs) via mechanochemical methods. For four isophthalic acid-based, alkoxide-functionalized organic ligands, optimal milling times were found to vary from 12 to 48 min. This work confirms that mechanochemical synthesis routes can be utilized to afford highly-crystalline, 2D MOFs.

Keywords

metal–organic frameworksmechanochemistry
Type
Technical Article
Information
Powder Diffraction , Volume 34 , Issue 2 , June 2019 , pp. 119 - 123
Copyright
Copyright © International Centre for Diffraction Data 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barreda, O., Bannwart, G., Yap, G. P. A., and Bloch, E. D. (2018a). “Ligand-based phase control in porous molecular assemblies,” ACS Appl. Mater. Interfaces 10, 11420–11424.Google Scholar
Barreda, O., Taggart, G., Rowland, C. A., Yap, G. P. A., and Bloch, E. D. (2018b). “Mechanochemical synthesis of porous molecular assemblies,” Chem. Mater. 30, 3975–3978.Google Scholar
Carrington, E. J., Vitorica-Yrezabal, I. J., and Brammer, L. (2014). “Crystallographic studies of gas sorption in metal–organic frameworks,” Acta Cryst. B70, 404–422.Google Scholar
Chen, Y.-Z., Zhangm, R., Jiao, L., and Jiang, H.-L. (2018). “Metal–organic framework-derived porous materials for catalysis,” Coord. Chem. Rev. 362, 1–23.Google Scholar
Crawford, D., Casaban, J., Haydon, R., Giri, N, Mcnally, T., and James, S. T. (2015). “Synthesis by extrusion: continuous, large-scale preparation of MOFs using little or no solvent,” Chem. Sci. 6, 1645–1649.Google Scholar
Davis, M. (2002). “Ordered porous materials for emerging applications,” Nature 417, 813–821.Google Scholar
Friscic, T. (2010). “New opportunities for materials synthesis using mechanochemistry,” J. Mater. Chem. 20, 7599–7605.Google Scholar
Kradeniz, B., Howarth, A. J., Stolar, T., Islamoglu, T., Dejanovic, I., Tireli, M., Wasson, M. C., Moon, S.-Y., Farha, O. K., Friscic, T., and Uzarevic, K. (2018). “Benign by design: green and scalable synthesis of zirconium UiO-66-metal–organic frameworks by water-assisted mechanochemistry,” ACS Sustainable Chem. Eng. 6, 15841–15849.Google Scholar
Lorzing, G. R., Trump, B. A., Brown, C. M., and Bloch, E. D. (2017). “Selective gas adsorption in highly porous chromium(II)-based metal–organic polyhedra,” Chem. Mater. 29, 8583–8587.Google Scholar
Mason, J. A., Veenstra, M., and Long, J. R. (2014). “Evaluating metal–organic frameworks for natural gas storage,” Chem. Sci. 5, 32–51.Google Scholar
Prochowicz, D., Nawrocki, J., Terlecki, M., Marynowski, W., and Lewinski, J. (2018). “Facile mechanosynthesis of the archetypal Zn-based metal–organic frameworks,” Inorg. Chem. 57, 13437–13442.Google Scholar
Son, W.-J., Kim, J., Kim, J., and Ahn, W.-S. (2008). “Sonochemical synthesis of MOF-5,” Chem. Commun. 0, 6336–6338.Google Scholar
Supplementary material: File

Barreda et al. supplementary material

Barreda et al. supplementary material 1

Download Barreda et al. supplementary material(File)
File 498.3 KB
Supplementary material: File

Barreda et al. supplementary material

Barreda et al. supplementary material 2

Download Barreda et al. supplementary material(File)
File 3.7 MB
Supplementary material: File

Barreda et al. supplementary material

Barreda et al. supplementary material 3

Download Barreda et al. supplementary material(File)
File 496.8 KB
Supplementary material: File

Barreda et al. supplementary material

Barreda et al. supplementary material 4

Download Barreda et al. supplementary material(File)
File 879.7 KB