Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2024-12-26T07:47:04.585Z Has data issue: false hasContentIssue false
  • English
  • Français

Fruits of Serendipity in Research of Titanium Compounds: from “Sodium Tianide” to Titanium Nitride Whiskers

Published online by Cambridge University Press:  10 January 2013

C. E. Bamberger
C. E. Bamberger
Affiliation:
Chemistry Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 37831-6119, U.S.A.
Get access Rights & Permissions [Opens in a new window]

Abstract

The usefulness of complementing the results of X-ray diffraction (XRD) with an independent technique such as Raman spectroscopy (RS) was demonstrated by the successful identification of the products (TiN and Na-titanates) from the reaction of TiO2 with NaCN. The study of other reactions of NaCN with several Ti-compounds to produce TiN powder led to the development of new syntheses reactions for known [TiP2O7, NaTi2(PO4)3 and NaxTiO2] and for new [(TiO)2P2O7, Na(TiO)PO4 and Na4(TiO)(PO4)2] compounds. The reaction of NaxTiO2 with NaCN produced TiN in the form of whiskers.

Type
Research Article
Information
Powder Diffraction , Volume 3 , Issue 4 , December 1988 , pp. 240 - 241
Copyright
Copyright © Cambridge University Press 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bamberger, C. E. (1982), J. Am. Ceram. Soc. 65, C–107.Google Scholar
Bamberger, C. E. (1986), React. Solids 2, 277–282.Google Scholar
Bamberger, C. E. and Begun, G. M. (1986), J. Am. Ceram. Soc. 69, C–95.Google Scholar
Bamberger, C.E. and Begun, G. M. (1987a), J. Am. Ceram. Soc. 70, C–48.Google Scholar
Bamberger, C. E. and Begun, G. M. (1987b), J. Less-Common Met. 134, 201–206.Google Scholar
Bamberger, C. E. and Begun, G. M. (1987c), React. Solids 4, 275–279.Google Scholar
Bamberger, C. E., Angelini, P. and Nolan, T. A. (1988), “Formation of TiN Whiskers by Reaction of Sodium-Titanium Bronze with Molten Sodium Cyanide,” J. Am. Cer. Soc. (in press).Google Scholar
Bamberger, C. E., Begun, G. M. and Cavin, O. B. (1988), J. Solid State Chem. 73, 317–324.CrossRefGoogle Scholar
Bamberger, C. E., Begun, G. M. and Heatherly, D. E. (1987), React. Solids 3, 165–170.Google Scholar
Guernsey, E. W. and Sherman, M. S. (1926), J. Am. Chem. Soc. 48, 695–704.Google Scholar
Powder Diffraction File (1984). Swarthmore, PA 19081, USA: International Centre for Diffraction Data.Google Scholar
Shushunov, V. A., Pavlov, A. M. and Fedykova, F. G. (1956), J. Appl. Chem. USSR (Engl. Transl.) 29, 1765–1771.Google Scholar
Skórski, R. (1950), Hutnik, 17, 226–231.Google Scholar
Villars, D. S. (1931), J. Am. Chem. Soc. 53, 405–411.Google Scholar