Hostname: page-component-78c5997874-mlc7c Total loading time: 0 Render date: 2024-11-13T13:09:58.089Z Has data issue: false hasContentIssue false
  • English
  • Français

Crystal data for Cs2KTbCl6 and Cs2KEuCl6 by powder X-ray diffraction

Published online by Cambridge University Press:  10 January 2013

M. E. Villafuerte-Castrejón ,
M. R. Estrada ,
L. Rosales ,
J. Gómez-Lara ,
J. Duque  and
R. Pomés
M. E. Villafuerte-Castrejón
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, A.P. 70-360, Ciudad Universitaria, Coyoacan 04510, México, D.F.
M. R. Estrada
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, A.P. 70-360, Ciudad Universitaria, Coyoacan 04510, México, D.F.
L. Rosales
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, A.P. 70-360, Ciudad Universitaria, Coyoacan 04510, México, D.F.
J. Gómez-Lara
Affiliation:
Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán 04510, México, D.F.
J. Duque
Affiliation:
Centro Nacional de Investigaciones Científicas, Apdo. 6990, Ciudad de la Habana, Cuba
R. Pomés
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN, Unidad Mérida. Km 6 Antigua carretera a Progreso; Apdo Postal No 73 Cordemex; 97310 Mérida Yuc, México
Get access Rights & Permissions [Opens in a new window]

Abstract

Two compounds of the elpasolite family (A2BLnX6), Cs2KTbCl6 and Cs2KEuCl6, were obtained {by evaporating to dryness a hot aqueous HCl solution of the appropriate chlorides [Morss etal., Inorg. Chem. 9, 1771 (1970)]} and characterized by powder X-ray diffraction. Title compounds are isostructural with cubic Rb2NaTmCl6 and correspond to the perovskite related structure with space group Fm3m, cell parameters 11.1294(6) and 11.1618(4) Å, V=1378.5(2), and V=1390.5(1) Å3, respectively.

Type
Research Article
Information
Powder Diffraction , Volume 11 , Issue 4 , December 1996 , pp. 281 - 283
Copyright
Copyright © Cambridge University Press 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)