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The contributions of Albert W. Hull to X-ray powder diffraction at one hundred years of his landmark publication

Published online by Cambridge University Press:  18 January 2017

José Miguel Delgado*
Affiliation:
Laboratorio de Cristalografía-LNDRX, Departamento de Química, Facultad de Ciencias, Universidad de Los Andes, Mérida 5101, Venezuela
*
a)Author to whom correspondence should be addressed. Electronic mail: [email protected]

Abstract

One hundred years ago X-ray powder diffraction, one of the premier techniques used in the characterization of materials, was invented. Its origins can be traced to two landmark contributions presented to the scientific community in 1916. They are the better known and celebrated work carried out by Paul Scherrer under the guidance of Peter W. Debye, at the University of Göttingen, Germany, and the lesser known work of Albert W. Hull performed at the Research Laboratory of the General Electric Company, Schenectady, NY, USA. The great contributions of Scherrer and Debye have been prominently recognized. They are presented in many textbooks and in technical and scientific articles published in the area of characterization of materials using powder diffraction techniques. The camera designed by them, later called “the Debye–Scherrer camera”, was used extensively for many years and the experimental setup (“the Debye–Scherrer geometry”) is still used today. On the other hand, the work performed by Hull has not been adequately appreciated and remembered. In this communication, an account of his contributions to X-ray powder diffraction and to crystallography is presented at 100 years of his landmark publication, which appeared in the first issue of Physical Review of 1917.

Type
Review Article
Copyright
Copyright © International Centre for Diffraction Data 2017 

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References

American Physical Society (1917). Proceeding of the 84th meeting. Phys. Rev. 9, 8396.CrossRefGoogle Scholar
Authier, A. (2013). Early Days of X-ray Crystallography (International Union of Crystallography, Oxford University Press, Oxford).CrossRefGoogle Scholar
Bish, D., Blake, D., Vaniman, D., Sarrazin, P., Bristow, T., Achilles, C., Dera, P., Chipera, S., Crisp, J., Downs, R. T., Farmer, J., Gailhanou, M., Ming, D., Morookian, J. M., Morris, R., Morrison, S., Rampe, E., Treimanl, A., and Yeng, A. (2014). “The first X-ray diffraction measurements on Mars,” IUCrJ 1, 514522.CrossRefGoogle ScholarPubMed
Bragg, W. H. (1915). “X-rays and crystal structure (Bakerian lecture),” Phil. Trans. R. Soc. 215, 253274.Google Scholar
Brittain, J. E. (2010). “Electrical engineering hall of fame, Albert W. Hull,” Proc. IEEE 98(4), 635637.CrossRefGoogle Scholar
Compton, A. H. (1915). “The distribution of the electrons in atoms,” Nature 95, 343344.CrossRefGoogle Scholar
Davey, W. P. (1921). “A new diffraction apparatus,” J. Opt. Soc. Am. 5(6), 479493.CrossRefGoogle Scholar
de Wolff, P. M. (1957). “On the determination of unit-cell dimensions from powder diffraction patterns,” Acta Crystallogr. 10, 590595.CrossRefGoogle Scholar
Debye, P. and Scherrer, P. (1916). “Interferenzen an regellos orientierten Teilchen im Röntgenlicht. I.,” Nachrichten von der Gesellschaft der Wissenschaften zu Göttingen, Math. Phys. Kl. 1–15 (1916). Also published under the same title in Physikalische Zeitschrift. 17, 277283.Google Scholar
Etter, M. and Dinnebier, R. E. (2014). “A century of powder diffraction: a brief history,” Z. Anorg. Allg. Chem. 640(15), 30153028.CrossRefGoogle Scholar
Ewald, P. P. (Ed.) (1963). Fifty Years of X-Ray Diffraction (International Union of Crystallography, Utrecht).Google Scholar
Hanawalt, J. D. and Rinn, H. W. (1936). “Identification of crystalline materials,” Ind. Eng. Chem. Anal. Ed. 8, 244250.CrossRefGoogle Scholar
Hanawalt, J. D., Rinn, H. W., and Frevel, L. K. (1938). “Chemical analysis by X-ray diffraction”, Ind. Eng. Chem. Anal. Ed. 10(9), 457512.CrossRefGoogle Scholar
Hull, A. W. (1917a). “The crystal structure of iron,” Phys. Rev. 9, 8487.Google Scholar
Hull, A. W. (1917b). “A new method of X-ray crystal analysis,” Phys. Rev. 10(6), 661696.CrossRefGoogle Scholar
Hull, A. W. (1918). “The dynatron: a vacuum tube possessing negative resistance,” Proc. Inst. Radio Eng. 6, 535.Google Scholar
Hull, A. W. (1919a). “The crystal structure of ferro-magnetic metals,” Phys. Rev. 14(6), 540541.Google Scholar
Hull, A. W. (1919b). “A new method of chemical analysis”, J. Am. Chem. Soc., 41(8), 11681175.CrossRefGoogle Scholar
Hull, A. W. (1921a). “The crystal structure of calcium”, Phys. Rev. 17(1), 4244.CrossRefGoogle Scholar
Hull, A. W. (1921b). “X-ray crystal analysis of thirteen common metals,” Phys. Rev. 17(5), 571588.CrossRefGoogle Scholar
Hull, A. W. (1921c). “Crystal structure of titanium, zirconium, cerium, thorium and osmium,” Phys. Rev. 18, 8889.Google Scholar
Hull, A. W. (1922). “Crystal structures of vanadium, germanium and graphite,” Phys. Rev. 20, 113113.Google Scholar
Hull, A. W. and Davey, W. P. (1921). “Graphical determination of hexagonal and tetragonal crystal structures from X-ray data,” Phys. Rev. 17, 549570.CrossRefGoogle Scholar
Ilyushin, A. S. and Kovalchuk, M. V. (2012). “The 100th anniversary of the discovery of X-ray diffraction,” Crystallogr. Rep. 57, 617627.CrossRefGoogle Scholar
Ito, T. (1949). “A general powder X-ray photography,” Nature 164(4174), 755756.CrossRefGoogle ScholarPubMed
Jenkin, J. (2008). William and Lawrence Bragg, Father and Son. The Most Extraordinary Collaboration in Science (Oxford University Press, Oxford), p. 356.Google Scholar
McLachlan, D. and Glusker, J. (Eds.) (1983). Crystallography in North America (American Crystallographic Association, Buffalo).CrossRefGoogle Scholar
Messick, J. (2012). “The history of the international centre for diffraction data”, Powder Diffr. 27(1), 3644.CrossRefGoogle Scholar
Runge, C. (1917). “Die Bestimmung eines Kristallsystems durch Röntgenstrahlen,” Phys. Z. 18, 509515.Google Scholar
Suits, G. (1960). “Willis Rodney Whitney, 1868–1958. A Biographical Memoir,” in the National Academy of Science webpage, Washington, DC: http://www.nasonline.org/publications/biographical-memoirs/memoir-pdfs/whitney-willis-r.pdf Google Scholar
Suits, C. G. and Lafferty, J. M. (1970). “Albert Wallace Hull, 1880–1966. A Biographical Memoir,” in the National Academy of Sciences webpage, Washington, DC: http://www.nasonline.org/publications/biographical-memoirs/memoir-pdfs/hull-albert.pdf Google Scholar
Visser, J. W. (1969). “A fully automatic program for finding the unit cell from powder data,” J. Appl. Crystallogr. 2, 8995.CrossRefGoogle Scholar