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Composition and genesis of rattlestones from Dutch soils as shown by Mössbauer spectroscopy, INAA and XRD

Published online by Cambridge University Press:  01 April 2016

J.J. van Loef
J.J. van Loef*
Affiliation:
Interfacultair Reactor Instituut, TU Delft, Mekelweg 15, 2629 JB DELFT, The Netherlands; fax +31-15-2788303

Abstract

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The chemical and mineralogical composition of rattlestones found near the main Dutch rivers has been studied by Mössbauer spectroscopy, INAA and XRD. Rattlestones are concretions of iron, formed in an environment of lateral iron accumulation, under the influence of periodical oxidation, around a fine core of ferruginous sediments, mainly clay and sand. The core has shrunk and detached itself from the mantle around it. 57Fe Mössbauer spectroscopy was applied to identify the iron oxides, among which goethite is predominant. The goethite crystallinity was investigated by measuring its magnetic properties and its crystallinity, which is poorest at the outer side of the stone. The latter is confirmed by the broadening of the different X-ray reflections. In addition, illite and vermiculite were identified by XRD; these clay minerals were found mainly in the core.

The elemental composition was determined by INAA. The iron content in the mantle is about 50% by weight and gradually decreases outwards, while the core contains 2–15% Fe by weight. Differences between rattlestones from the Middle Pleistocene East of the Meuse river and those from the Late Pleistocene North of it are the absence of lepidocrocite and a richer mineralogy in the former.

It is concluded that the rattlestones are formed around a fine clayey core. Groundwater supplied the iron and other (trace) elements for the genesis. It is unlikely that rattlestones are the result of oxidation of siderite.

Keywords

crystallinitygoethiteiron accumulationlepidocrociteMössbauer spectroscopyrattlestonessideritetrace elements
Type
Research Article
Information
Netherlands Journal of Geosciences , Volume 79 , Issue 1 , March 2000 , pp. 59 - 71
Copyright
Copyright © Stichting Netherlands Journal of Geosciences 2000

References

Adams, F.D., 1938. The birth and development of the geological sciences. Ballière, Tindall and Cox (London): 506 pp.Google Scholar
Bromehead, C.N., 1947. Aetites or the eagle-stone. Antiquity 21: 16–21.CrossRefGoogle Scholar
Coey, J.M., 1988. Magnetic properties of iron in soil iron oxides and clay minerals. In: Stucki, J.W., Goodman, B.A. & Schwertmann, U. (eds.): Iron in soils and clay minerals. Riedel, D. (Dordrecht): 397–466.CrossRefGoogle Scholar
Cornell, R.M. & Schwertmann, U., 1996. The iron oxides: structure, properties, reactions, occurrence and uses. Verlag Chemie (Weinheim): 573 pp.Google Scholar
Edelman, Th. & De Bruin, M., 1986. Background values of 32 elements in Dutch topsoil, determined with non-destructive neutron activation analysis. In: Assink, J.W. & Van den Brink, W.J. (eds.): Contaminated soil. Martinus Nijhoff Publishers (Dordrecht): 89–99.CrossRefGoogle Scholar
Fitzpatrick, R.W., 1988. Iron compounds as indicators of pedogenic processes: examples from the southern hemisphere. In: Stucki, J.W., Goodman, B.A. & Schwertmann, U. (eds.): Iron in soils and clay minerals. Riedel, D. (Dordrecht): 351–395.CrossRefGoogle Scholar
Huisman, D.J., 1998. Geochemical characterization of subsurface sediments in the Netherlands. Thesis Agricultural University Wageningen: 175 pp.Google Scholar
Huisman, D.J., Vermeulen, F.J.M., Baker, J., Veldkamp, A., Kroonenberg, S.B. & Klaver, G.Th, 1997. A geological interpretation of heavy metal concentrations in soils and sediments in the southern Netherlands. Journal of Geochemical Exploration 59: 163–174.CrossRefGoogle Scholar
Huisman, D.J., Van Os, B.J.H., Klaver, G.Th, & Van Loef, J.J., 1999. Redistribution of REE in aquifers in the Netherlands. In: Armannsson, H. (ed.): Geochemistry of earth’s surface. Balkema, A.A. (Rotterdam): 511–514.Google Scholar
Jackson, J.A., 1997. Glossary of geology (4th ed.). American Geological Institute (Alexandria): 769 pp.Google Scholar
Kuzmann, E., Nagy, S., Vértes, A., Weiszburg, T.G. & Garg, V.K., 1998. Geological and mineralogical applications of Mössbauer spectroscopy. In: Vértes, A., Kuzmann, E., Nagy, S., Weiszburg, T.G. & Garg, V.K. (eds.): Nuclear methods in mineralogy and geology. Plenum Press (New York): 285–376.CrossRefGoogle Scholar
McLennan, S.M., 1989. Rare earth elements in sedimentary rocks: influence of provenance and sedimentary processes. In: Lipin, B.R. & McKay, G.A. (eds.): Geochemistry and mineralogy of rare earth elements. Reviews in Mineralogy 21: 169–200.CrossRefGoogle Scholar
Meyer, B., 1979. Die Entcarbonatierungsrotung als Bodengenetischer Teilprozess. Mitteilungen der deutschen Bodenkundlichen Gesellschaft 28: 705–708.Google Scholar
Michard, A., Beaucaire, C. & Michard, G., 1987. Uranium and rare earth elements in CO2-rich waters from Vals-les Bains (France). Geochimica et Cosmochimica Acta 51: 901–909.CrossRefGoogle Scholar
Moura, M.L. & Kroonenberg, S.B., 1990. Geochemistry of Quaternary fluvial and eolian sediments in the southeastern Netherlands. Geologie en Mijnbouw 69: 359–373.Google Scholar
Munsell Soil Color Charts, 1954. Munsell Company Inc. (Baltmore).Google Scholar
Murad, E. & Bowen, L.H., 1987. Magnetic ordering in Al-rich goethites: influence of crystallinity. American Mineralogist 72: 194–200.Google Scholar
Murad, E., 1988. Magnetic properties of iron in soil iron oxides and clay minerals. In: Stucki, J.W., Goodman, B.A. & Schwertmann, U. (eds.): Iron in solids and clay minerals. Riedel, D. (Dordrecht): 309–352.CrossRefGoogle Scholar
Murad, E., 1996. Magnetic properties of microcrystalline iron (III) and related materials as reflected in their Mössbauer spectra. Physics and Chemistry of Minerals 23: 248–262.CrossRefGoogle Scholar
Parry, S.J., 1991. Activation spectrometry in chemical analysis. J.Wiley & Sons (New York) 243 pp.Google Scholar
Pettijohn, F.J., 1975. Sedimentary rocks. Harper & Row (New York): 628 pp.Google Scholar
Riezebos, P.A., Bisdom, E.B.A. & Boersma, O., 1978. Composite grains in Maas sediments: a survey and a discussion of their opaque components. Geologie en Mijnbouw 57: 417–431.Google Scholar
Schwertmann, U., 1988a. Some properties of soil and synthetic iron oxides. In: Stucki, J.W., Goodman, B.A. & Schwertmann, U. (eds.): Iron in solids and clay minerals. Riedel, D. (Dordrecht): 203–250.CrossRefGoogle Scholar
Schwertmann, U., 1988b. Occurrence and formation of iron oxides in various pedoenvironments. In: Stucki, J.W., Goodman, B.A. & Schwertmann, U. (eds.): Iron in solids and clay minerals. Riedel, D. (Dordrecht): 267–308.CrossRefGoogle Scholar
Schwertmann, U. & Taylor, R.M., 1971. The in vitro transformation of soil lepidocrocite to goethite. In: Pseudogley and gley. Transactions of Committees V and VI of the International Society of Soil Science (Stuttgart-Hohenheim) : 45–54.Google Scholar
Schwertmann, U. & Taylor, R.M., 1972. The transformation of lepidocrocite to goethite. Clays and Clay Minerals 20: 151–158.CrossRefGoogle Scholar
Senkayi, A.L., Dixon, J.B. & Hossner, L.R., 1986. Todorokite, goethite and hematite: alteration products of siderite in East Texas lignite overburden. Soil Science 142: 36–42.CrossRefGoogle Scholar
Van Breemen, N. & Buurman, P., 1998. Soil formation. Kluwer Academic Publishers (Dordrecht): 377 pp.CrossRefGoogle Scholar
Van der Burg, W.J., 1969. The formation of rattle stones. Palaeogeography, Palaeoclimatology, Palaeoecology 6: 105–124.CrossRefGoogle Scholar
Van der Burg, W.J., 1971. The climatological factors. Palaeogeography, Palaeoclimatology, Palaeoecology 7: 297–308.CrossRefGoogle Scholar
Van der Kraan, A.M., 1972. Mössbauer effect studies of superparamagnetic α-FeOOH and α-Fe2O3 . Thesis Delft University of Technology; Krips (Meppel): 121 pp.Google Scholar
Van der Kraan, A.M. & Van Loef, J.J., 1966 Superparamagnetism and submicroscopic α-FeOOH particles observed by the Mössbauer effect. Physics Letters 20: 614–616.CrossRefGoogle Scholar
Wedepohl, K.H. (ed.), 1978. Handbook of geochemistry. Springer (New York) : 5 volumes.Google Scholar