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Published online by Cambridge University Press: 26 February 2011
We have investigated laser ablation of excited atoms from the ferroelectrics LiNbO3 and KNbO3 at 308 nm. Comparisons of the yields for O*, K* and Nb* from pure and undoped KNbO3 show the effects of changing intensity, surface condition and irradiation time on the yield of excited atoms. Below about 20 GW cm−2, the mechanisms for production of excited atoms differ among the various species; above that intensity, the production of a dense electron-hole plasma appears to impart a collective character to the ablation mechanism.