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Ultraviolet Photodetector Fabricated from 3D WO3 Nanowires/Reduced Graphene Oxide Composite Material

Published online by Cambridge University Press:  17 February 2014

Dali Shao
Affiliation:
Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180, USA
Mingpeng Yu
Affiliation:
Department of Mechanical, Aerospace & Nuclear Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180, USA Department of Chemistry, Laboratory of Bio-organic Phosphorus, Tsinghua University, Beijing 100084, China.
Jie Lian
Affiliation:
Department of Mechanical, Aerospace & Nuclear Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180, USA
Shayla Sawyer
Affiliation:
Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180, USA
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Abstract

An Ultraviolet (UV) photodetector with high responsivity and relative fast response speed was fabricated from three dimensional WO3 nanowires/reduced graphene oxide (3D WO3 NWs/RGO) composite materials. The 3D WO3 NDs/GN composite was synthesized using a facile three-step synthesis. First, the Na2WO4/Graphene Oxide (GO) precursor was synthesized by homogeneous precipitation. Second, the Na2WO4/GO precursor was transformed into H2WO4/GO composites by acidification. Finally, the H2WO4/GO composites were reduced to 3D WO3 NWs/RGO via hydrothermal reduction process. A maximum photoresponsivity of 4.2 A/W at 374 nm was observed under 20 V bias. The UV photodetector showed relative fast transient response, which is at least 2 orders of magnitude faster than UV photodetectors fabricated from WO3 nanowires. The good photoresponsivity and fast transient response are attributed to improved carrier transport and collection efficiency through graphene.

Type
Articles
Copyright
Copyright © Materials Research Society 2014 

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