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Topochemical Modification of Layered Perovskites

Published online by Cambridge University Press:  01 February 2011

Jong-Lak Choi ,
Elisha Josepha ,
Xiao Zhang  and
John Wiley
Jong-Lak Choi
Affiliation:
[email protected], University of New Orleans, Department of Chemistry and the Advanced Materials Research Institute, New Orleans, Louisiana, United States
Elisha Josepha
Affiliation:
[email protected], University of New Orleans, Department of Chemistry and the Advanced Materials Research Institute, New Orleans, Louisiana, United States
Xiao Zhang
Affiliation:
[email protected], University of New Orleans, Department of Chemistry and the Advanced Materials Research Institute, New Orleans, Louisiana, United States
John Wiley
Affiliation:
[email protected], University of New Orleans, Department of Chemistry and the Advanced Materials Research Institute, New Orleans, Louisiana, United States
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Abstract

Topochemical reaction strategies based on two-step intercalation methods are studied. Reactions involving reductive followed by oxidative intercalation are quite effective in making new compounds; the synthesis and characterization of (A2Cl)LaNb2O7 (A = Rb, Cs) are presented. An alternative synthetic route, oxidative followed by reductive intercalation, is also discussed.

Keywords

intercalationlayeredoxide
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1148: Symposium PP – Solid-State Chemistry of Inorganic Materials VII , 2008 , 1148-PP01-03
Copyright
Copyright © Materials Research Society 2009

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References

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