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Ti-Modified Niobium-Silicide Based Directionally Solidified in-situ Composites

Published online by Cambridge University Press:  15 February 2011

B. P. Bewlay
Affiliation:
General Electric Company, Corporate Research and Development Center, Schenectady, NY 12301
M. R. Jackson
Affiliation:
General Electric Company, Corporate Research and Development Center, Schenectady, NY 12301
H. A. Lipsitt
Affiliation:
Department of Mechanical and Materials Engineering, Wright State University, Dayton, OH 45435.
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Abstract

This paper examines microstructure-property relationships in high-temperature directionally solidified (DS) in-situ composites based on Nb silicides, such as Nb3Si and Nb5Si3. These in-situ composites are based on the Nb3Si-Nb binary eutectic, and are alloyed with Ti. They were prepared using cold crucible Czochralski crystal growth. Ternary Nb-Ti-Si alloys with Ti concentrations from 9 to 45%, and Si concentrations from 10 to 25%, were directionally solidified to generate aligned two- and three-phase composites containing a Nb solid solution with Nb3Si and Nb5Si3 silicides. Fracture toughness values generally greater than 10 MPa√m were measured in these composites. For a given Si concentration, the fracture toughness of the Ti-containing composites was increased ∼ 6 MPa√m over that of the binary alloy composites. The effects of Si concentration, and a range of Nb:Ti ratios, on microstructure, phase equilibria, and fracture toughness were examined.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

[1] Subramanian, P.R., Mendiratta, M.G., and Dimiduk, D.M., MRS Symp. Proc. 322, 491502 (1994).Google Scholar
[2] Bewlay, B.P., Jackson, M.R., Reeder, W.J., and Lipsitt, H.A., MRS Svmp. Proc. 364, 943948 (1995).Google Scholar
[3] Subramanian, P.R., Mendiratta, M.G., and Dimiduk, D.M., JOM 48 (1), 3337 (1996).Google Scholar
[4] Jackson, M.R., Bewlay, B.P., Rowe, R.G., Skelly, D.W., and Lipsitt, H.A., JOM 48 (1), 3846 (1996).Google Scholar
[5] Bewlay, B.P., Jackson, M.R. and Lipsitt, H.A., Accepted for publication in the Journal of Phase Equilibria, October 1996.Google Scholar
[6] Chang, K-M., Bewlay, B.P., Sutliff, J. A. and Jackson, M.R., JOM 44 (6), 5965 (1992).Google Scholar
[7] Rigney, J.D., Singh, P.R., and Lewandowski, J.J., MRS Symp. Proc. 322, 502509 (1994).Google Scholar
[8] Bewlay, B.P., Jackson, M.R. and Lipsitt, H.A., accepted for publication in Metall, and Mater. Trans., August 1996.Google Scholar
[9] Imgram, A.G., Bartlett, E.S. and Ogden, H.R., Trans. Met. Soc. AIME 227, 131 (1963).Google Scholar