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Temperature-Dependent Dynamics of Microconfined Cs2

Published online by Cambridge University Press:  10 February 2011

B. J. Loughnane ,
R. A. Farrer ,
L. A. Deschenes  and
J. T. Fourkas
B. J. Loughnane
Affiliation:
Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02167
R. A. Farrer
Affiliation:
Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02167
L. A. Deschenes
Affiliation:
Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02167
J. T. Fourkas
Affiliation:
Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02167
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Abstract

Femtosecond optical-heterodyne detected Raman-induced Kerr effect spectroscopy (OHD-RIKES) has been used to study the reorientational dynamics of CS2 in microporous glasses over a wide range of temperatures. Microconfinement is shown to affect the behavior of the liquid at all the temperature studied. The results are interpreted in terms of a two-state model of the confined liquid.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 464: Symposium FF – Dynamics in Small Confining Systems III , 1996 , 263
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1. Liu, G., Li, Y. and Jonas, J., J. Chem. Phys. 95, p. 6892 (1991).Google Scholar
2. Zhang, J. and Jonas, J., J. Phys. Chem. 97, p. 8812 (1993).Google Scholar
3. Nikiel, L., Hopkins, B. and Zerda, T. W., J. Phys. Chem. 94, p. 7458 (1990).Google Scholar
4. Wallen, S. L., Nikiel, L., Yi, J. and Jonas, J., J. Phys. Chem. 99, p. 15421 (1995).Google Scholar
5. Pissis, P., Laudai, J., Daoukaki, D. and Kyritsis, A., J. Non-Cryst. Solids 171, p. 201 (1994).Google Scholar
6. Bellisent-Funel, M.-C., Lal, J. and Bosio, L., J. Chem. Phys. 98, p. 4246 (1993).Google Scholar
7. Warnock, J., Awschalom, D. D. and Schafer, M. W., Phys. Rev. B 34, p. 475 (1986).Google Scholar
8. Deeg, F. W. and Schwalb, G. in Dynamics in Small Confining Systems II, edited by Drake, J.M., Klafter, J., Kopelman, R. and Troian, S. M. (Mater. Res. Soc. Proc. 366, Pittsburgh, PA 1995), p. 213–224.Google Scholar
9. Jeffrey Brinker, C. and Scherer, George W., Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, Academic Press, San Diego, 1990.Google Scholar
10. McMorrow, Dale and Lotshaw, William T., J. Phys. Chem. 95, p. 10395 (1991).Google Scholar
11. Yan, Yong-Xin and Nelson, K. A., J. Chem. Phys. 87, p. 6240 (1987).Google Scholar