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Synthesis of Oligomeric P-Phenyleneimine by Self-Condensation Reaction of a Novel Monomer

Published online by Cambridge University Press:  10 February 2011

A. Afzali  and
J. D. Gelorme
A. Afzali
Affiliation:
IBM Research Division, T.J. Watson Research Center, Yorktown Heights, N.Y. 10598
J. D. Gelorme
Affiliation:
IBM Research Division, T.J. Watson Research Center, Yorktown Heights, N.Y. 10598
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Abstract

A new approach for the synthesis of poly(phenylenimines) and related conjugated polymers is presented. A novel bifunctional monomer, N-Boc-indoaniline 4 is synthesized as shown in scheme I. Thermolysis of the latter, either as solid, thin film or in solution of high boiling solvents, leads to polycondensation of the bifucntional monomer and results in the formation of poly(phenyleneimine) or its reduced form. Scope and limitation of this approach in the synthesis of various poly(aryleneimines) is also described.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 413: Symposium W – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials III , 1995 , 513
Copyright
Copyright © Materials Research Society 1996

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References

REFERENCES

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