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Synthesis of a Novel Donor, BTFE-DMB, and Electrical Properties of its Iodine Salt

Published online by Cambridge University Press:  25 February 2011

Makoto Mizutani ,
Keiji Tanaka ,
Kiyoshi Ikeda  and
Kazushige Kawabata
Makoto Mizutani
Affiliation:
Central Research Laboratories, Idemitsu Kosan Co., Ltd. 1280 Kamiizumi, Sodegaura, Chiba 299–02, Japan.
Keiji Tanaka
Affiliation:
Central Research Laboratories, Idemitsu Kosan Co., Ltd. 1280 Kamiizumi, Sodegaura, Chiba 299–02, Japan.
Kiyoshi Ikeda
Affiliation:
Central Research Laboratories, Idemitsu Kosan Co., Ltd. 1280 Kamiizumi, Sodegaura, Chiba 299–02, Japan.
Kazushige Kawabata
Affiliation:
Central Research Laboratories, Idemitsu Kosan Co., Ltd. 1280 Kamiizumi, Sodegaura, Chiba 299–02, Japan.
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Abstract

1, 4-Bis [2-(tetrathiafulvalen-2-yl)ethenyl] -2, 5-dimethylbenzene (BTFE-DMB) is synthesized and its structure is found to be planar. The single crystal of its iodine salts undergoes a metal-insulator transition about 180K. The compaction pellets of the iodine salts show the current dependent resistive anomaly under high pressure.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 541
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Garito, A. F. and Heeger, A. J., Ace. Chem. Res., 7, 232 (1974).Google Scholar
2. Bryce, M. R. and Moore, A. J., Tetrahedron Lett., 29, 1075 (1988).Google Scholar
3. Tatemitsu, H., Nishikawa, E., Sakata, Y. and Misumi, S., Synth. Metals, 19, 565–568 (1987).Google Scholar
4. Yosida, Z., Kawase, T., Awaji, H., Sugimoto, I., Sugimoto, T., and Yoneda, S., Tetrahedron Lett., 24, 3469 (1983).Google Scholar
5. Mizutani, Makoto, Tanaka, Keiji, Ikeda, Kiyoshi, Kawabata, Kazushige, Synth. Metals, 46, 201–205(1991).Google Scholar
6. Melby, L. R., Harder, R. J., Hertler, W. R., Mahler, W., Benson, R. E., and Mochel, W. E. J. Am. Chem. Soc,. 84, 3374(1962).Google Scholar
7. Ferraris, J. P., Cowan, D. O., Walatka, V. V. Jr, and Perlstein, J. H., J. Am. Chem. Soc, 95, 948(1973)Google Scholar