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Synthesis and Structural Characterization of Ferromagnetic Au/Co Nanoparticles

Published online by Cambridge University Press:  03 June 2014

Nabraj Bhattarai*
Affiliation:
Department of Physics and Astronomy, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA.
Subarna Khanal
Affiliation:
Department of Physics and Astronomy, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA.
Daniel Bahena
Affiliation:
Department of Physics and Astronomy, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA.
Robert L. Whetten
Affiliation:
Department of Physics and Astronomy, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA.
Miguel Jose-Yacaman
Affiliation:
Department of Physics and Astronomy, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA.
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Abstract

The synthesis of bimetallic magnetic nanoparticles is very challenging because of the agglomeration and non-uniform size. In this paper, we present the synthesis of monodispersed 3-5 nm sized thiolated bimetallic alloyed Au/Co nanoparticles with decahedral and icosahedral shape, their characterization using Cs-corrected scanning transmission electron microscopy (STEM) and magnetic measurements using superconducting quantum interference device (SQUID) magnetometer. The Z-contrast imaging and energy dispersive X-ray spectroscopy (EDS) mapping showed an inhomogeneous alloying with minor segregation between Au and Co at nanoscale and the SQUID measurement exhibited the ferromagnetic behavior.

Type
Articles
Copyright
Copyright © Materials Research Society 2014 

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References

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