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Synthesis and Chemical Properties of Dye-Doped Mesoporous Transition Metal Oxides

Published online by Cambridge University Press:  15 February 2011

I. Honma ,
H.S. Zhou  and
S.C. Moon
I. Honma
Affiliation:
Electrotechnical Laboratory, AIST, Umezono 1-1-4, Tsukuba, Ibaraki, 305-8568, JapanTel: +81-298-54-5797, fax: +81-298-54-5805, e-mail: [email protected]
H.S. Zhou
Affiliation:
Electrotechnical Laboratory, AIST, Umezono 1-1-4, Tsukuba, Ibaraki, 305-8568, JapanTel: +81-298-54-5797, fax: +81-298-54-5805, e-mail: [email protected]
S.C. Moon
Affiliation:
RITE, Research Institute of Innovative Technology for the Earth, Sourakugun, Kyoto619, Japan
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Abstract

Self-assembled functional dye molecules in mesoporous transition metal oxides have been synthesized directly by Pc (phthalocyanine) molecules doped within hexadecyltrimethylammonium bromide (C16 TMA) micelles assembled with oxide frameworks such as Vanadia (VOX), FeOx, MoO3 and WO3 to produce Pc-doped mesostructured materials. The Pc molecules were heavily doped inside the mesoporous channels and dye's optical absorption were measured. Pc molecules in contact with mesoporous transition metal oxides interfaces are optically excited and provide reductive electrons to water molecules to decompose into hydrogen by visible light exposures.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 549: Symposium FF – Advanced Catalytic Materials - 1998 , 1998 , 131
Copyright
Copyright © Materials Research Society 1999

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References

1. Beck, J.S., US Pat., 1991, 5, 507, 296.Google Scholar
2. Kresge, C.T., Leonowicz, M.E., Roth, W.J. and Vartuli, J.C., US Pat., 1992, 5, 098, 684.Google Scholar
3. Kresge, C.T., Leonowicz, M.E., Vartuli, J.C. and Beck, J.S., Nature, 1992, 359, 710.Google Scholar
5. Monnier, A., Schuth, F., Huo, Q., Kumar, D., Margolese, D., Maxwell, R. S., Stucky, G. D., Krishnamurty, M., Petroff, P., Firouzi, A., Janicke, M. and Chmelka, B.F., Science, 1993, 261, 1299.Google Scholar
6. Firouzi, A., Kumar, D., Bull, L., Besier, M.T., Sieger, P., Huo, Q., Walker, S.A., Zasadzinski, J.A., Glinka, C., Nicol, J., Margolese, D., Stucky, G.D. and Chmelka, B.F., Science, 1995, 267, 1138.Google Scholar
7. Chen, Cong-Yan, Li, H.-X. and Davis, M.E., Microporous Materials, 1993, 2, 17.Google Scholar
8. Huo, Q., Margolese, D.I., Ciesla, Ulrike, Demuth, D.G., Feng, P., Gier, T.E., Sieger, P., Firouzi, A., Chmelka, B.F., Schuth, F. and Stucky, G.D., Chem. Mater., 1994, 6, 1176.Google Scholar
9. Antonelli, D.M. and Ying, J.Y. Angew. Chem. Int. Ed. Engl., 1995, 34, 2014.Google Scholar
10. Luca, V., Maclachlan, D.J., Hook, J.M. and Withers, R., Chem. Mater., 1995, 7, 2220.Google Scholar
11. Stein, A., Fendorf, M., Jarvie, T.P., Mueller, K.T., Benesi, A.J. and Mallouk, T.E., Chem. Mater., 1995, 7, 304.Google Scholar
12. Ciesla, U., Demuth, D., Leon, R., Petroff, P., Stucky, G.D., Unger, K. and Schuth, F., J. Chem. Soc. Commun., 1994, 1387.Google Scholar
13. Janauer, G.G., Dobley, A., Guo, J., Zavalij, P. and Whittingham, M.S., Chem. Mater., 1996, 8, 2096.Google Scholar
14. Aksay, I.A., Trau, M., Manne, S., Honma, I., Yao, N., Zhou, L., Fenter, P., Eisenberger, P.E. and Gruner, S.M., Science, 1996, 273, 892.Google Scholar
15. Yang, H., Coombs, N., Sokolov, I. and Ozin, G.A., Nature, 1996, 381, 589.Google Scholar
16. Yang, H., Kuperman, A., Coombs, N., Afara, S.M. and Ozin, G.A., Nature, 1996, 381, 589.Google Scholar