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Synthesis and Characterization of Multiferroic Composites Based on Manganate Perovskite Ceramics

Published online by Cambridge University Press:  01 February 2011

Gonbao Song
Affiliation:
[email protected], University of Aveiro, DECV and CICECO, Aveiro, 3810-193, Portugal
Jian Li
Affiliation:
[email protected], DECV and CICECO, Aveiro, 3810-193, Portugal
Andrei Kholkin
Affiliation:
[email protected], University of Aveiro, DECV and CICECO, Aveiro, 3810-193, Portugal
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Abstract

In this paper, phase separation and crystal structure of (x) La0.625Sr0.375MnO3 − (1-x) LuMnO3 system (LSMO-LMO), and (1-x) La0.9Ca0.1MnO3-(x) LuMnO3 system (LCMO-LMO) were studied by XRD and SEM. The results confirm that there are solid solutions in both of these two systems. There is a solid solution of monoclinic phase of space group P1121/a for x=0.980∼1.0 in LSMO-LMO system. There is a solid solution of hexagonal phase of space group P63cm for x=0.0∼0.24 in LCMO-LMO. Selected compositions were tested in terms of their magnetization, dielectric constant and ferroelectric properties at low temperatures.

Type
Research Article
Copyright
Copyright © Materials Research Society 2008

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References

[1] Wang, J. et al. , , Science 299, 1719 (2003).Google Scholar
[2] Rado, G.T. and Folen, V.J., Observation of the Magnetically Induced Magnetoelectric Effect and Evidence for Antiferromagnetic Domains. J. Phys. Rev. Lett., 1961, 7, 310311.Google Scholar
[3] Alshin, B.I. and Astrov, D.N., Magnetoelectric effect in titanium oxide ti2o3. J. Phys.—JETP 1963, 17, 809811.Google Scholar
[4] Rado, G T., Observation and Possible, Mechanisms of Magnetoelectric Effects in a Ferromagnet. J. Phys. Rev. Lett., 1964, 13, 335337.Google Scholar
[5] Ascher, E, Rieder, H, Schmid, H and Stossel, H., Some properties of ferromagnetoelectric nickel-iodine boracite Ni3B7O13I. J. Appl. Phys., 1966, 37, 14041405.Google Scholar
[6] Santoro R, P, Segal D, J and Newnham R, E, Magnetic properties of Magnetic Properties of LiCoP4 and LiNiPO4 . J. Phys. Chem. Solids, 1966, 27, 11921193.Google Scholar
[7] Watanabe, T and Kohn, K., Magnetoelectric effect and low-temperature transition of PbFe0.5Nb0.5O3 single-crystal. J. Phase Trans. 1989, 15, 5768.Google Scholar
[8]. Park, S. et al. , Phys. Rev. Lett. 92, 167206 (2004).Google Scholar
[9] Rietveld, H.M., Line profiles of neutron powder-diffraction peaks for structure refinement. Acta Crystallogr. 1967, 229, 151152.Google Scholar
[10] Young, R. A., Sakthivel, A., Moss, T. S., and Paiva-Santos, C. O. DBWS-9411—an upgrade of the DBWS*.* programs for Rietveld re- finement with PC and mainframe computers. J. Appl. Crystallogr. 1995, 28, 336367.Google Scholar
[11] Huang, Q., Santoro, A., Lynn, J.W., Erwin, R.W., Borchers, J.A., Peng, J.L., Greene, R.L.. Phys. Rev. B 55, 22(1997)14987.Google Scholar