Published online by Cambridge University Press: 25 February 2011
The morphology of small islands of TiSi2 and ZrSi2 on Si(100) is investigated and compared to larger islands in terms of a solid state capillarity model. The silicide islands are formed by deposition of very thin layers of titanium and zirconium (3–50Å) followed by an anneal at high temperatures (700–1200 °C). SEM and cross-sectional HRTEM are used to study respectively the surface and interface morphology. It is found that the C49-phase for TiSi2 is stable for layers as thin as 8Å, and annealing temperatures as high as 1200°C. An explanation for the fact that the formed islands align parallel to the Si<110> directions is given in terms of interplanar lattice spacings.