Published online by Cambridge University Press: 25 February 2011
Reports of enhanced sintering rates associated with microwave heating may be due to nonthermal lattice fluctuation statistics. Recent theoretical analyses reviewed in this paper confirm the feasibility of this phenomenon for a wide variety of situations involving very different microwave absorption mechanisms. For materials with weak microwave absorption coefficients, the effect is expected to be uniformly distributed throughout the volume. For strongly absorbing materials, however, the effect is expected to be concentrated near the material surface, with a characteristic exponential penetration depth of Lnt ∼ 10 - 100 μm. An “observable” nonthermal effect depends on the relative magnitude of the microwave electric field strength |E| and the lattice ion energy relaxation rate γ with the most pronounced effects occurring for larger values of |E| and smaller values of γ.