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Solution Phase Synthesis of Semiconductor Nanowires

Published online by Cambridge University Press:  01 February 2011

Katherine L. Hull ,
James W. Grebinski ,
Jing Zhang ,
Thomas H. Kosel  and
Masaru Kuno
Katherine L. Hull
Affiliation:
Department of Chemistry and Biochemistry, Notre Dame, IN 46556 Notre Dame Radiation Laboratory, and Notre Dame, IN 46556
James W. Grebinski
Affiliation:
Notre Dame Radiation Laboratory, and Notre Dame, IN 46556
Jing Zhang
Affiliation:
Department of Electrical Engineering Notre Dame, IN 46556
Thomas H. Kosel
Affiliation:
Department of Electrical Engineering Notre Dame, IN 46556
Masaru Kuno
Affiliation:
Department of Chemistry and Biochemistry, Notre Dame, IN 46556 Notre Dame Radiation Laboratory, and Notre Dame, IN 46556
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Abstract

The solution phase synthesis of narrow diameter CdSe and PbSe nanowires (NWs) is described. Crystalline NWs with lengths between 1–10 μm are obtained using a seeded solution approach, whereby NW growth is catalyzed by Au/Bi core/shell nanoparticles (NPs). A gold biphasic reduction step results in 1.5 (3) nm diameter Au NPs and is followed by the thermolysis of trialkylbismuthines to yield low melting, bimetallic particles with diameters less than 3 nm. These Au/Bi NPs are catalytically active towards the growth of similar diameter CdSe NWs (∼7 nm) that exhibit quantum confinement effects. By varying the ratio of Cd (or Pb) to Se, both straight and branched NWs can be obtained, with branched structures including v-shapes, tripods, and y-shapes in the case of CdSe and t-shapes in the case of PbSe. Structural characterization shows that both straight and branched CdSe NWs grow along either the <111> zinc blende (ZB) or <0001> wurtzite (W) directions. Conversely, PbSe has a rocksalt crystal structure, and both straight and branched NWs grow along <100> directions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 848: Symposium FF – Solid-State Chemistry of Inorganic Materials V , 2004 , FF8.6
Copyright
Copyright © Materials Research Society 2005

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