Hostname: page-component-78c5997874-lj6df Total loading time: 0 Render date: 2024-11-02T23:23:57.195Z Has data issue: false hasContentIssue false

Self-Compression and Diamond Nucleation In Irradiated Carbon Onions - A Theoretical Model

Published online by Cambridge University Press:  15 February 2011

M. Zaiser*
Affiliation:
Max-Planck-Institut für Metallforschung, Heisenbergstr. 1, D-70569 Stuttgart, Germany, [email protected]
Get access

Abstract

The nucleation of small diamond crystals during irradiation of spherical graphitic particles (’bucky onions’) is discussed. A mechanism for irradiation-induced self-compression of such ’onions’ is proposed. It is demonstrated that this may yield pressures which are sufficiently high for diamond formation. The theoretical results are in good agreement with experimental findings.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Banhart, F. and Ajayan, P. M., Nature 382, 433 (1996).Google Scholar
2. Banhart, F., J. Appl. Phys. 81, 3440 (1996).Google Scholar
3. Banhart, F., Füller, T., Redlich, Ph., and Ajayan, P. M., Chem. Phys. Letters 269, 349, (1998).Google Scholar
4. Wesolowski, P., Lyutovich, Y., Banhart, F., Carstanjen, H.D. and Kronmiiller, H., Appl. Phys. Letters 71, 1948 (1997).Google Scholar
5. Zaiser, M. and Banhart, F., Phys. Rev. Letters 79, 3680 (1997).Google Scholar
6. Lyutovich, Y. and Banhart, F., Appl. Phys. Letters (submitted).Google Scholar
7. Lyutovich, Y. (unpublished data).Google Scholar
8. Sigle, W. and Redlich, Ph., Phil. Mag. Letters 76, 125 (1997).Google Scholar
9. Lynch, R. W. and Drickamer, H. G., J. Chem. Phys. 44, 181 (1966).Google Scholar
10. Stone, A. J. and Wales, D. J., Chem. Phys. Letters 128, 501 (1986).Google Scholar
11. Bates, K. R. and Scuseria, R. E., Theor. Chem. Acc. 99, 29 (1998).Google Scholar
12. Regueiro, M. Nunez, Monceau, P. and Hodeau, J.-L., Nature 355, 237 (1992).Google Scholar