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Rheological Characterization of a Sol-Gel Process for the Preparation of High Tc Superconductors

Published online by Cambridge University Press:  21 February 2011

S. A. Khan
Affiliation:
Bellcore, 331 Newman Springs Road, Red Bank, NJ 07701
B. G. Bagley
Affiliation:
Bellcore, 331 Newman Springs Road, Red Bank, NJ 07701
P. Barboux
Affiliation:
Bellcore, 331 Newman Springs Road, Red Bank, NJ 07701 Universite P. et. M. Curie, 4 Place Jussieu, 75005 Paris
F. E. Torres
Affiliation:
Princeton University, Chemical Engineering Dept., Princeton, NJ 08540
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Abstract

Superconducting thick films of yttrium-based cuprates can be prepared using a sol-gel technique. Rheological measurements on the precursors are used to identify processing parameters that can lead to better film properties. Steady and dynamic experiments reveal a direct correlation between the properties of the precursor, the final product, and the “age” of the yttrium component used in the precursor. Measurements support a proposed mechanism relating the “age” of the yttrium to the other properties and help to establish a processing methodology to obtain effective superconducting properties.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

1. Bednorz, J.G. and Muller, K.A., Z. Phys., B64, 189 (1986).Google Scholar
2. Wu, M.K., Ashburn, J.R., Torng, C.J., Hor, P.H., Meng, R.L., Gao, L., Huang, Z.J., Wang, Y.Q., and Chu, C.W., Phys.Rev. Lett., 58, 908 (1987).Google Scholar
3. Cava, R.J., Batlogg, B., van Dover, R.B., Murphy, D.W., Sunshine, S., Siegrist, T., Remieka, J.P., Rietman, E.A., Zahurak, S., Espinosa, G., Phys Rev. Lett., 58, 1676 (1987).Google Scholar
4. Bagley, B.G., Greene, L.H., Barboux, P., Tarascon, J.M., Venkatesan, T., Chase, E.W., Chan, S.W., Feldman, W.L., Wilkins, B.J., Khan, S.A. and Giroud, M., in Advances in Superconductivity: Proc. Ist International Symp. Superconductivity (ISS'88), 1988, Nagoya, edited by Kitazawa, K. and Ishiguro, T. (Springer Verlag, Tokyo, 1989), p.477.Google Scholar
5. Barboux, P., Valente, I., Tarascon, J.M., Khan, S., Shokoohi, F., Henry, M., Morineau, R. and Bagley, B.G., in Superconductors: Relationships Between Properties, Structure, and Solid State Chemistry, edited by Torrance, J.B., Kitazawa, K., Tarascon, J.M., Jorgensen, J.R. and Thompson, M. (Mater. Res. Soc. Pittsburg, PA), submitted.Google Scholar
6. Khan, S.A., Barboux, P., Bagley, B.G., Torres, F.E., J. Non-Crystalline Solids (in press).Google Scholar
7. Barboux, P., Tarascon, J.M., Greene, L.H., Hull, G.W. and Bagley, B.G., J. Appl. Phys., 63, 2725 (1988).Google Scholar
8. Bird, R.B., Armstrong, R.C. and Hassager, O., Dynamics of Polymeric Liquids, Vol. 1: Fluid Mechanics, 2nd ed. (Wiley, New York, 1987), pp. 112.Google Scholar
9. Berne, B.J. and Pecora, R., Dynamic Light Scattering, (Wiley, New York, 1976).Google Scholar
10. Khan, S.A., Barboux, P., Bagley, B.G. and Tarascon, J.M., Appl. Phys. Lett., 53 (8), 700 (1988).Google Scholar