Hostname: page-component-745bb68f8f-l4dxg Total loading time: 0 Render date: 2025-01-26T04:57:05.326Z Has data issue: false hasContentIssue false
  • English
  • Français

Poly(SNS) Electrochemical Synthesis and Processability

Published online by Cambridge University Press:  10 February 2011

T. F. Otero ,
S. Villanueva ,
E. Brillas  and
J. Carrasco
T. F. Otero
Affiliation:
Laboratorio de Electroquímica, Facultad de Químicas, Universidad del País Vasco, P.O. Box 1072, 20080 San Sebastián, SPAIN, [email protected]
S. Villanueva
Affiliation:
Laboratorio de Electroquímica, Facultad de Químicas, Universidad del País Vasco, P.O. Box 1072, 20080 San Sebastián, SPAIN, [email protected]
E. Brillas
Affiliation:
Departament de Química Física; Departament d'Enginyeria Química i Metal.lúrgia, Facultad de Química, Universitat de Barcelona, Martí i Franqués, 1. 08028 Barcelona, SPAIN.
J. Carrasco
Affiliation:
Departament de Química Física; Departament d'Enginyeria Química i Metal.lúrgia, Facultad de Química, Universitat de Barcelona, Martí i Franqués, 1. 08028 Barcelona, SPAIN.
Get access

Abstract

The flow of an anodic current density of 0.5 mA. cm−2 through a 5 mmol/l solution of 2,5-di-(2-thienyl)pyrrole (SNS), in acetonitrile, gives dark-violet and uniform polymer films coating the platinum electrode in presence of different electrolytes. The process is named either electropolymerization or electrogeneration.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 600: Symposium FF – Electroactive Polymers , 1999 , 167
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Roncali, J., Gamier, F., Lemaire, M., Garreau, R., Synth. Met., 15, 323, (1986).10.1016/0379-6779(86)90081-0Google Scholar
2. McLeod, G.G., Mahboubian-Jones, M.G.B., Oethrick, R.A., Watson, S.D., Truong, N.D., Galin, J.C., J. François, Polymer, 27, 455, (1986).Google Scholar
3. Zhao, M.T., Samoc, M., Singh, B.P., Prasai, P.N., J. Phys. Chem., 93, 7916, (1989).10.1021/j100360a036Google Scholar
4. Ferraris, J.P., Hanlon, T.R., Polymer, 30, 1319, (1989).10.1016/0032-3861(89)90054-2Google Scholar
5. Reynolds, J.R., Pomerants, M., in Electroresponsive Molecular and Polymeric Systems, edited by Dekker, Marcel (New York, 1991), pp. 187–256.Google Scholar
6. Sørensen, A.R., Overgaad, L., Johannsen, T., Synth. Met., 55–57, 1626, (1993).Google Scholar
7. Soshi, M.V., Henler, C., Cava, M.P., Cain, J.L., Bakker, M.G., Mc-Kinley, A.J., Metzeger, R.M., J. Chem. Soc. Perkin Trans., 2, 1081, (1993).Google Scholar
8. Carrasco, J., Otero, T.F., Brillas, E., Montilla, M., J. Electroanal. Chem., 418, 115, (1996).Google Scholar
9. Brillas, E., Montilla, M., Carrasco, J., Otero, T.F., J. Electroanal. Chem., 418, 123, (1996).Google Scholar
10. Carrasco, J., Figueras, A., Otero, T.F., Brillas, E., Synth. Met., 61, 253, (1993).Google Scholar
11. Otero, T.F., Carrasco, J., Figueras, A., Brillas, E., J. Electroanal. Chem., 370, 231, (1994).Google Scholar
12. Otero, T.F., Brillas, E., Carrasco, J., Figueras, A., Mat. Res. Symp. Proc., 328, 799, (1994).Google Scholar
13. Brillas, E., Carrasco, J., Figueras, A, Urpí, F., Otero, T.F., J. Electroanal. Chem., 392, 55, (1995).Google Scholar
14. Wynberg, H., Metselaar, J., Synth. Commun., 14(1), 1, (1984).Google Scholar
15. Otero, T.F., Villanueva, S., Brillas, E., Carrasco, J., Acta Polym., 49, 433, (1998).Google Scholar