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Polymer Physics Of High Temperature Polymers For Second Order Nonlinear Optics

Published online by Cambridge University Press:  16 February 2011

C. Y. Stacey Fu ,
Duane B. Prdddy Jr ,
Greg D. Lyle ,
James E. Mcgrath  and
Hilary S. Lackritz
C. Y. Stacey Fu
Affiliation:
Purdue University, School of Chemical Engineering, West Lafayette, IN 47907–1283
Duane B. Prdddy Jr
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and NSF Science and Technology Center: High Performance Polymeric Adhesives, Blacksburg, VA 24061–0344
Greg D. Lyle
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and NSF Science and Technology Center: High Performance Polymeric Adhesives, Blacksburg, VA 24061–0344
James E. Mcgrath
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and NSF Science and Technology Center: High Performance Polymeric Adhesives, Blacksburg, VA 24061–0344
Hilary S. Lackritz*
Affiliation:
Purdue University, School of Chemical Engineering, West Lafayette, IN 47907–1283
*
* To whom correspondence should be addressed
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Abstract

A new class of high temperature polymeric materials capable of second order nonlinear optical effects has been developed and characterized. These polymers, Bisphenol A-poly (arylene ether) phosphine oxides (Bis A-PEPO), F6 Bis A-PEPO, phenolphthalein•PEPO (PP-PEPO), and phenolphthaIein-anilide•PEPO (PP-PEPO), doped with nonlinear optical chromophores are being examined using second harmonic generation. Corona poling is used to orient the chromophores into the noncentrosymmetric structure required to obtain the second harmonic signal. These high glass transition temperature (>200°C) polymers have strong hydrogen bonding sites that can interact with the chromophores. This work describes the basic polymer physics including local Mobility, chromophore/polymer interactions, and polymer steric effects that control the thermal and temporal stability of chromophore orientation in these guest-host polymeric systems.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 547
Copyright
Copyright © Materials Research Society 1994

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References

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