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Published online by Cambridge University Press: 21 February 2011
The feasibility of utilizing NF3-halocarbon mixed etchants to anisotropically etch tungsten silicide structures has been investigated. CVD tungsten silicide was etched with various mixtures of CF3Cl and CF2Cl3 to which 0 to 50 vol percent NF3 was added under a variety of conditions. Anisotropy, undercutting, and notching were evaluated using cross-sectional SEM. Relative etch rates and selectivity for each gas mixture were also determined. Halocarbon residues were investigated using XPS and related to side wall passivity.