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Photocatalytic activities of layered intercalated materials H2NiTi4O10/TiO2 under UV and visible light irradiation

Published online by Cambridge University Press:  15 February 2011

Jihuai Wu*
Affiliation:
Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, 362021, China.
Yunfang Huang
Affiliation:
Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, 362021, China.
Taohai Li
Affiliation:
Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, 362021, China.
Jianming Lin
Affiliation:
Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, 362021, China.
Miaoliang Huang
Affiliation:
Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, 362021, China.
Yuelin Wei
Affiliation:
Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, 362021, China.
*
*To whom correspondence should be addressed
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Abstract

H2NiTi4O10/TiO2 intercalated compound was fabricated by successive intercalation reactions of H2NiTi4O10 with n-C6H13NH2/C2H5OH mixed solution and acid TiO2 sol, followed by irradiating with a high-pressure mercury lamp. H2NiTi4O10, a layered perovskite type compound with TiO2-loading, exhibited a high activity for decomposition of methyl orange under UV and visible light irradiation. The experimental results showed that methyl orange was degraded with the decomposition ratio of 59.0 % by using H2NiTi4O10/TiO2 as photocatalyst under visible light ( > 420 nm) irradiation for 24 h. The H2NiTi4O10/TiO2 possessed higher photocatalytic activity than those commercial titania powder (Degussa P-25) which showed the decomposition ratio just only 24% under same condition.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

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