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Patterning PETN and HMX using Dip Pen Nanolithography

Published online by Cambridge University Press:  26 February 2011

Omkar Nafday ,
Brandon Weeks ,
Jason Haaheim  and
Ray Eby
Omkar Nafday
Affiliation:
[email protected], Texas Tech University, 6th Street and Canton,, Dept. of Chemical Engineering, Lubbock, TX, 79409, United States, 806-786-5298
Brandon Weeks
Affiliation:
[email protected], Texas Tech University, United States
Jason Haaheim
Affiliation:
[email protected], NanoInk Inc., United States
Ray Eby
Affiliation:
[email protected], NanoInk Inc.
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Abstract

Recently there has been a focused effort to develop reliable nanoscopic writing and reading capabilities. Dip-pen nanolithography (DPN) has emerged as a convenient method to deliver nanoscale materials onto a substrate by leveraging scanning probe microscopy capability. A new application for the DPN method is the field of microdetonics which is the microscale decomposition and study of reactions of explosives. Results are presented for patterning pentaerythritol tetranitrate (PETN) and cyclotetramethylene tetranitramine (HMX) on silicon and mica substrates. The ultimate goal is to pattern both energetic materials in nanoscale registry and investigate their reaction and decomposition at the nanoscale due to heating or shock initiation. In addition to patterning of high explosives, a discussion on the effect of surface energy on patterning rates is investigated. This knowledge will be applicable to inks beyond high explosives.

Keywords

nanostructurelithography (deposition)nanoscale
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 896: Symposium H – Multifunctional Energetic Materials , 2005 , 0896-H05-06
Copyright
Copyright © Materials Research Society 2006

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