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Published online by Cambridge University Press: 10 February 2011
Deposition of elemental S on Si(100)2×1 surfaces at room temperature changes the reconstructed Si(100)2×1 to its original bulk-terminated Si(100)l×l surface. Sulfur forms initially a (2×l) on the Si(100)2×l surface and subsequently a (l×1) on the Si(100)l×l. Above 1ML, sulfur is diffused into the Si bulk near the surface. The sticking coefficient of S on Si(100) surface is constant up to 2 ML. Deposition of S at RT up to 1 ML increases the work function of the surface by about.3±0.05 eV. Above I ML, as the S is diffused into the Si bulk, the work function decreases.