Hostname: page-component-586b7cd67f-dlnhk Total loading time: 0 Render date: 2024-11-24T16:33:18.829Z Has data issue: false hasContentIssue false

Ordered 3D Hexagonal Mesoporous Silica Membranes: Synthesis and Characterization

Published online by Cambridge University Press:  11 February 2011

Michaela Klotz
Affiliation:
Laboratoire CNRS / Saint-Gobain «Surface du Verre et Interface» UMR 125; 39 Quai Lucien Lefranc; F- 93303 Aubervilliers cedex, France
Sophie Besson
Affiliation:
Laboratoire CNRS / Saint-Gobain «Surface du Verre et Interface» UMR 125; 39 Quai Lucien Lefranc; F- 93303 Aubervilliers cedex, France
Christian Ricolleau
Affiliation:
Laboratoire de Minéralogie, Cristallographie, UMR 7590; Université Paris VI et Paris VII, 4 place Jussieu, F-75252 Paris cedex 05, France
Florence Bosc
Affiliation:
Institut Européen des Membranes, UMR 5635; CC047, Université Montpellier II, F-34095 Montpellier cedex 5, France
André Ayral
Affiliation:
Institut Européen des Membranes, UMR 5635; CC047, Université Montpellier II, F-34095 Montpellier cedex 5, France
Get access

Abstract

A ceramic membrane with an ordered mesoporous top layer has been developed. The active layer possesses a close-packed hexagonal network of spherical pores. Results on permeation of helium and argon through the membrane are presented and correlated with the structural and textural properties of the top layer. New insights are given on the porosity of this close-packed hexagonal structure.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartuli, J.C. and Beck, J.S., Nature 359 (1992) 710.Google Scholar
2. Dabadie, T., Ayral, A., Guizard, C., Cot, L., Robert, J.C. and Poncelet, O.,. Mat. Res. Soc. Symp. Proc. 346 (1994) 849.Google Scholar
3. Ayral, A., Balzer, C., Dabadie, T., Guizard, C. and Julbe, A., Catalysis Today 25 (1995) 219.Google Scholar
4. Dabadie, T., Ayral, A., Guizard, C., Cot, L., Robert, J.C. and Poncelet, O., Proceedings of the Third International Conference on Inorganic Membranes, July 1994, Worchester, USA, Ma, Y.H. (Ed.), 3rd ICIM-Worchester polytechnic Institute, Worchester, USA, 1994, 411.Google Scholar
5. Dabadie, T., Ayral, A., Guizard, C., Cot, L. and Lacan, P., J. Mater. Chem. 6 (1996) 1789.Google Scholar
6. Klotz, M., Ayral, A., Guizard, C. and Cot, L., J. Mater. Chem. 10 (2000) 663.Google Scholar
7. Klotz, M., Albouy, P.A., Ayral, A., Ménager, C., Grosso, D., Cabuil, V., Babonneau, F. and Guizard, C., Chem. Mater. 12 (2000) 1721.Google Scholar
8. Klotz, M., Ayral, A., Guizard, C. and Cot, L., Separation and Purification Technology 25 (2001) 71.Google Scholar
9. Besson, S., Ricolleau, C., Gacoin, T., Jacquiod, C., Boilot, J-P., J. Phys. Chem. B (2000), 104, 12095.Google Scholar
10. Ayral, A., El Mansouri, A., Vieira, M.P. and Pilon, C., J. Mater. Sci. Lett. 17 (1998) 883.Google Scholar
11. Besson, S., Gacoin, T., Ricolleau, C., Jacquiod, C., Boilot, J-P., Nano Letters (2002) Vol. 2, No. 4, 409.Google Scholar
12. Besson, S., pH D Thesis, Ecole Polytechnique 2002 Google Scholar
13. Burggraaf, A.J., Cot, L., Fundamentals of Inorganic Membrane Science and Technology, Membrane Science and Technology Series, 4, Elsevier, Amsterdam, 1996.Google Scholar