Published online by Cambridge University Press: 28 February 2011
The amorphous dielectrics a-C:H and BN were deposited on III–V semiconductors.Optical band gaps as high as 3 eV were measured for a-C:H generated by C4 H10 plasmas; a comparison was made with bad gaps obtained from films prepared by CH4 glow discharges.The ion beam deposited BN films exhibited amorphous behavior with band gaps on the order of 5 eV.
Film compositions were studied by Auger electron spectroscopy (AES), x-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS).The optical properties were characterized by ellipsometry, UV/VIS absorptiofr, and IR reflection and transmission.Etching rates of a-C:H subjected to O2 discharges were determined.