Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-28T06:06:33.948Z Has data issue: false hasContentIssue false
  • English
  • Français

Nuclear waste immobilization into structure of zirconolite by Complex Sol Gel Process

Published online by Cambridge University Press:  17 June 2014

Tomasz Smoliński ,
Andrzej Deptuła ,
W. Lada ,
Tadeusz Olczak ,
Andrzej G. Chmielewski  and
Fabio Zaza
Tomasz Smoliński
Affiliation:
Institute of Nuclear Chemistry and Technology (INCT), 03-195 Warsaw, Poland
Andrzej Deptuła
Affiliation:
Institute of Nuclear Chemistry and Technology (INCT), 03-195 Warsaw, Poland
W. Lada
Affiliation:
Institute of Nuclear Chemistry and Technology (INCT), 03-195 Warsaw, Poland
Tadeusz Olczak
Affiliation:
Institute of Nuclear Chemistry and Technology (INCT), 03-195 Warsaw, Poland
Andrzej G. Chmielewski
Affiliation:
Institute of Nuclear Chemistry and Technology (INCT), 03-195 Warsaw, Poland
Fabio Zaza
Affiliation:
ENEA-Casaccia Research Centre, UTPRA-GEOC SP011,Via Anguillarese 301,00123 Rome Italy
Get access

Abstract

Zirconolite (CaZrTi2O7) is one of the components of Synroc materials, which are regarded throughout the world nuclear as the second generation of high-level nuclear waste forms. The zirconolite phase was synthesized by a sol-gel method, with one variant of the method making use of ascorbic acid as a strong complexing agent. Into the structure of the zirconolite was incorporated 10 mol% Sr. Undoped and doped samples were examined by thermal analyses and X-ray diffraction. Addition of ascorbic acid to the sols lowered the firing temperature and promoted formation of the zirconolite phase.

Keywords

sol-gelTiwaste management
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1683: Symposium S – Actinides—Basic Science, Applications and Technology , 2014 , mrss14-1683-s04-05
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Ringwood, A.E., Kesson, S.E., Ware, N.G., Hibberson, W.O., and Major, A., Geochem. J. 13, 141 (1979).CrossRefGoogle Scholar
Ringwood, A.E., Mineral. Mag. 49 [April], 159 (1985).CrossRefGoogle Scholar
Yudintsev, S.V., Stefanovsky, S.V., and Ewing, R.C., in Chemistry of Inorganic Actinide Compounds, edited by Krivovichev, S.V., Burns, P.C., and Tananaev, I.G. (Elsevier, Amsterdam, 2007) pp. 457–490.CrossRefGoogle Scholar
Ringwood, A.E., Oversby, V.M., Kesson, S.E., Sinclair, W., Ware, N., Hibberson, W., and Major, A., Nucl. Chem. Waste Management 2, 287 (1981).CrossRefGoogle Scholar
Ojovan, M.I. and Lee, W.E., An Introduction to Nuclear Waste Immobilization, Vol. 1. (Elsevier, London, 2005) p. 316.Google Scholar
Woignier, T., Reynes, J., Phalippou, J., and Dussossoy, J.L., J. Sol-Gel Sci. Technol. 19, 833 (2000).CrossRefGoogle Scholar
Deptuła, A., Olczak, T., Łada, W., Sartowska, B., Chmielewski, A.G., Casadio, S., Alvani, C., Croce, F., Goretta, K.C., and Di Bartolomeo, A., in CIMTEC 2002, 10th International Ceramics Congress, Part A, edited by Vincenzini, P. (Techna Srl, Faenza, 2003) pp. 341–352.Google Scholar
Deptula, A., Lada, W., Olczak, T. Lanagan, M.T., Dorris, S.E., Goretta, K.C., and Poeppel, R.B., “Method for preparing of high temperature superconductors,” Polish Patent 172,618 (1997).Google Scholar
Deptuła, A., Goretta, K.C., Olczak, T., Łada, W., Chmielewski, A.G., Jakubaszek, U., Sartowska, B., Alvani, C., Casadio, S., and Contini, V., in Mater. Res. Soc. Symp. 900E, O09–10.1–6 (Mater. Res. Soc., Pittsburg, PA, 2006).Google Scholar
Moltyaner, G.I., Klukas, M.H., Takeda, S., Kotzer, T.G., and Yamazaki, L.S., “Advection dispersion modeling of tritium and chloride migration in a shallow sandy aquifer at the Chalk River Laboratories,” in Use of Isotopes for Analyses of Flow and Transport Dynamics in Groundwater Systems, Results of a Co-ordinated Research Project: 1996–1999 (IAEA, Vienna, 2000).Google Scholar
Smoliński, T., Deptuła, A., Olczak, T., Łada, W., Brykała, M., Wojtowicz, P., Wawszczak, D., Rogowski, M., and Zaza, F., J. Radioanalytical Nucl. Chem. 299, 675 (2014).CrossRefGoogle Scholar