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Nonlinear Optical Properties Of Substituted Stilbazolium-MPS3 Intercalation Compounds

Published online by Cambridge University Press:  16 February 2011

Pascal G. Lacroix ,
Rene Clement ,
Keitaro Nakatani ,
Isabelle Ledoux  and
Joseph Zyss
Pascal G. Lacroix
Affiliation:
Laboratoire de Chimie Inorganique, U.R.A. 420, Institut de Chimie Moléculaire d'Orsay, Université Paris-sud, 91405 Orsay, (France).
Rene Clement
Affiliation:
Laboratoire de Chimie Inorganique, U.R.A. 420, Institut de Chimie Moléculaire d'Orsay, Université Paris-sud, 91405 Orsay, (France).
Keitaro Nakatani
Affiliation:
Laboratoire de Physicochimie des Rayonnements, Orsay, (France).
Isabelle Ledoux
Affiliation:
C.N.E.T., Bagneux, (France).
Joseph Zyss
Affiliation:
C.N.E.T., Bagneux, (France).
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Abstract

We have investigated intercalation into optically transparent MPS3 (M = Mn, Cd) phases as a way towards spontaneous poling of cationic chromophores. Two nano-composite Materials of formula M0.86PS3 (dimethylamino-N-Methyl stilbazolium)0.28 were synthezised, and an efficiency up to 750 times that of urea was recorded in the cadmium intercalate. An additional interest arises from the possibility to associate NLO properties with the magnetization of the host lattice in the case of MnPS3 below 40 K.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 613
Copyright
Copyright © Materials Research Society 1994

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References

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