Hostname: page-component-7bb8b95d7b-5mhkq Total loading time: 0 Render date: 2024-09-06T11:22:23.798Z Has data issue: false hasContentIssue false
  • English
  • Français

New Version of Laser Device Materials for Developing Diffraction Beam Modulators; Novel Nano -periodic Structures

Published online by Cambridge University Press:  31 January 2011

Kyung Choi  and
Kenneth Shea
Kyung Choi
Affiliation:
[email protected], University of California, Chemistry, Irvine, California, United States
Kenneth Shea
Affiliation:
[email protected], University of California, Chemistry, Irvine, California, United States
Get access

Abstract

Cro/CrOx-doped hybrid glasses are designed to develop novel laser device materials by inserting alkylene spacers between inorganic oxides. In TEM images, morphology of the organically modified hybrid glasses reveals highly arranged nano-periodic patterns. The nano-patterns observed from the hybrid glass based on alkylene-bridged xerogel are sustained over substantial domains and appears to arise from modified glassy lattice fringes. In electron diffraction pattern, it also shows the circled diffraction patterns arise from Cro/CrOx. In laser experiments, the hybrid glass shows a new optical property, which generates a huge acoustic wave; the diffraction efficiency (45 %) of the modified glass is higher than that of methanol (25 %); it means that the compressibility of the solid type of glass is as effective as the liquid. The hybrid glass shows a new optical property that hitherto hasn’t been found and could be useful for developing diffraction beam modulators.

Keywords

acoustic emissionlasernanostructure
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1176: Symposium Y – Nanocrystalline Materials as Precursors for Complex Multifuntional Structures through Chemical Transformations and Self Assembly , 2009 , 1176-Y06-12
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

(1) (a) Shea, K. J.;Loy, D. A.; Webster, O. W. Chem. Mater. 1989, 1, 572. (b)Shea, K. J.;Loy, D. A.; Webster, O. W. J Am Chem. Soc. 1992, 114, 6700 Google Scholar
(2) (a) Corriu, R. J. P.; Moreau, J. J. E.; Thepot, P.; Wong, C. M. M. Chem. Mater. 1992, 4, 1217.Google Scholar
(b) Corriu, R. J. P.; Thepot, T.; Mang, M. W. C. J. Mater. Chem. 1994, 4, 987.Google Scholar
(3) (a) Loy, D. A.; Shea, K. J. Chem. Rev. 1995, 95, 1431. (b) Shea, K. J.; Loy, D. A. MRS Bulletin 2001, 26, 368.Google Scholar
(4) Choi, K. M.; Shea, K. J. Photonic Polymer Systems, Fundamentals, Methods, and Applications. edited by Wise, D. L. et al. World Scientific Publishing Co. 1998, 49, 437.Google Scholar
(5) Choi, K. M.; Shea, K. J. Chem. Mater. 1993, 5, 1067.Google Scholar
(6) Choi, K. M.; Shea, K.J. J. Phys. Chem. 1994, 98, 3207.Google Scholar
(7) Choi, K. M.; Shea, K. J. J. Am. Chem. Soc. 1994, 116, 9052.Google Scholar
(8) Choi, K. M.; Hemminger, J. C.; Shea, K. J. J. Phys. Chem. 1995, 99, 4720.Google Scholar
(9) Choi, K. M.; Shea, K. J. J. of Sol-Gel Science and Technology 1995, 5, 143.Google Scholar
(10) Oviett, H. W.; Shea, K. J.; Kalluri, S.; Shi, Y.; Steier, W. H.; Dalton, L. R. Chem Mater. 1995, 7, 493.Google Scholar