Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-24T22:45:09.460Z Has data issue: false hasContentIssue false
  • English
  • Français

Nanostructured LB Films Developed from Ferrocenylthioamide and Ferrocenylselenoamide Compounds

Published online by Cambridge University Press:  06 February 2014

Rosa E. Lazo-Jiménez ,
María C. Ortega-Alfaro ,
José G. López- Cortés ,
José A. Chávez-Carvayar ,
Jordi Ignés-Mullol ,
Francesc Sagués ,
Violeta Álvarez-Venicio  and
María P. Carreón-Castro
Rosa E. Lazo-Jiménez
Affiliation:
Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México (UNAM), Circuito Exterior, C.P. 04510, Ciudad Universitaria. D.F., México.
María C. Ortega-Alfaro
Affiliation:
Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México (UNAM), Circuito Exterior, C.P. 04510, Ciudad Universitaria. D.F., México.
José G. López- Cortés
Affiliation:
Instituto de Química, Universidad Nacional Autónoma de México (UNAM), Circuito Exterior, C.P. 04510, Ciudad Universitaria. D.F., México.
José A. Chávez-Carvayar
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México (UNAM), Circuito Exterior, C.P. 04510, Ciudad Universitaria. D.F., México.
Jordi Ignés-Mullol
Affiliation:
Department of Chemistry-Physics, IN2UB, University of Barcelona, Martí Franqués 1, 08028. Barcelona, Spain.
Francesc Sagués
Affiliation:
Department of Chemistry-Physics, IN2UB, University of Barcelona, Martí Franqués 1, 08028. Barcelona, Spain.
Violeta Álvarez-Venicio
Affiliation:
Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México (UNAM), Circuito Exterior, C.P. 04510, Ciudad Universitaria. D.F., México.
María P. Carreón-Castro
Affiliation:
Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México (UNAM), Circuito Exterior, C.P. 04510, Ciudad Universitaria. D.F., México.
Get access

Abstract

In this work, the synthesis of two amphiphilic π-conjugated compounds such as ferrocenylthioamide and ferrocenylselenoamide, with the general formula FcC=MNH(CH2)15CH3 with M = S or Se, are reported. The ferrocenyl group is a donor moiety forming a π-conjugated system with the amides of sulfur and selenium; both elements have also bioactivity with pharmacological interest. These two compounds formed Langmuir (L) monolayers at the air-water interface, which were characterized by isotherms of surface pressure versus molecular area (π-A) and compression/expansion cycles (hysteresis curves); Brewster angle microscopic images were also obtained. By using the Langmuir-Blodgett method molecular monolayers were transferred onto glass substrates. These nanostructures, in form of Langmuir-Blodgett (LB) films, were characterized through atomic force microscopy (AFM).

Keywords

filmnanostructurese
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1613: Symposium 4D – New Trends in Polymer Chemistry and Characterization-2013 , 2014 , pp. 67 - 72
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Dynarowicz-Latka, P., Dhanabalan, A., Oliveira, O.N., Adv. Colloid Interface 91, 221 (2001).CrossRefGoogle Scholar
Amer, W. A. et al. ., J. Inorg. Organomet. Polym. 20, 605 (2010).CrossRefGoogle Scholar
Fery-Forgues, S. and Delavaux-Nicot, B., J. Photoch. Photobiol. A 132, 137 (2000).CrossRefGoogle Scholar
Sakakibara, K. et al. ., Biomacromolecules 8, 1657 (2007).CrossRefGoogle Scholar
Lee, Y.K. et al. ., Carcinogenesis 31, 1092–1099 (2010).CrossRefGoogle Scholar
Sandoval-Sánchez, C. et al. ., J. Organomet. Chem. 694, 3692 (2009).CrossRefGoogle Scholar
Gutiérrez-Hernández, A. I. et al. ., J. Med. Chem. 2, A-L (2012).Google Scholar
López-Cortés, J.G. et al. ., J. Organomet. Chem. 690, 2229 (2005).CrossRefGoogle Scholar
Giner-Casares, J.J., Brezesinski, G., Formatex Research Center, Badajoz, Spain, 1007 (2012).Google Scholar
Ybert, C., Lu, W., Möller, G., Knobler, C.M., J. Phys. Chem. B 106, 2004 (2002).CrossRefGoogle Scholar