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Multiphase Polymer Networks with Shape-Memory

Published online by Cambridge University Press:  31 January 2011

Steffen Kelch ,
Marc Behl ,
Stefan Kamlage  and
Andres Lendlein
Steffen Kelch
Affiliation:
[email protected], Sika Technology, Tueffenwies 16, Zurich, 8048, Switzerland
Marc Behl
Affiliation:
[email protected], GKSS Research Centre Geesthacht GmbH, Institute of Polymer Research, Teltow, Germany
Stefan Kamlage
Affiliation:
[email protected], GKSS Research Centre Geesthacht GmbH, Institute of Polymer Research, Teltow, Germany
Andres Lendlein
Affiliation:
[email protected], United States
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Abstract

Tailoring of properties and functions of shape-memory polymer networks to the requirements of specific applications demands a knowledge-based approach. A comprehensive database enabling the analysis of structure-property relationships is obtained by the systematic variation of molecular parameters. In detail we investigated the influence of the nature of thermal transition on the shape-memory behavior of polymer networks. Furthermore, additional amorphous phases were introduced enabling tailoring of elastic properties especially in the temporary shape as a consequence of the formed polymer morphology. Enabling higher elasticity, adjustable hydrolytic degradability, and the possibility to tailor the transition temperature of shape-memory to a temperature between room temperature and body temperature are considered to be substantial steps to improve the applicability of these active polymers in medicine.

Keywords

polymermemorysecond phases
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1190: Symposium NN – Active Polymers , 2009 , 1190-NN01-06
Copyright
Copyright © Materials Research Society 2009

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References

[1] Lendlein, A. Kelch, S. Functionally Graded Materials Viii 492–493 (2005) 219-223.Google Scholar
[2] Lendlein, A. Kelch, S. Angewandte Chemie-International Edition 41 (2002) 2034–2057.10.1002/1521-3773(20020617)41:12<2034::AID-ANIE2034>3.0.CO;2-M3.0.CO;2-M>Google Scholar
[3] Behl, M. Lendlein, A. Soft Matter 3 (2007) 58–67.10.1039/B610611KGoogle Scholar
[4] Behl, M. Lendlein, A. Materials Today 10 (2007) 20–28.10.1016/S1369-7021(07)70047-0Google Scholar
[5] Liu, C. Qin, H. Mather, P. T. Journal of Materials Chemistry 17 (2007) 1543–1558.10.1039/b615954kGoogle Scholar
[6] Yakacki, C. M. Shandas, R. Lanning, C. Rech, B. Eckstein, A. Gall, K. Biomaterials 28 (2007) 2255–2263.10.1016/j.biomaterials.2007.01.030Google Scholar
[7] Lendlein, A. Schmidt, A. M. Langer, R. Proceedings of the National Academy of Sciences of the United States of America 98 (2001) 842–847.Google Scholar
[8] Kelch, S. Steuer, S. Schmidt, A. M. Lendlein, A. Biomacromolecules 8 (2007) 1018–1027.10.1021/bm0610370Google Scholar
[9] Choi, N. Y. Kelch, S. Lendlein, A. Advanced Engineering Materials 8 (2006) 439–445.10.1002/adem.200600020Google Scholar
[10] Lendlein, A. Schmidt, A. M. Schroeter, M. Langer, R. Journal of Polymer Science Part a-Polymer Chemistry 43 (2005) 1369–1381.10.1002/pola.20598Google Scholar
[11] Kelch, S. Choi, N. Y. Wang, Z. Lendlein, A. Advanced Engineering Materials 10 (2008) 494–502.10.1002/adem.200700339Google Scholar