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Microstructures of Glassy and Metastable Crystalline Phases Formed From FE-C- Ternary Alloys

Published online by Cambridge University Press:  15 February 2011

Erhard Hornbogen
Affiliation:
Institut für Werkstoffe, Ruhr-Universität Bochum, 4630 Bochum, FRG
Ingo Schmidt
Affiliation:
Institut für Werkstoffe, Ruhr-Universität Bochum, 4630 Bochum, FRG
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Abstract

Fe-C-base alloys were rapidly cooled from the liquid and then reheated from ambient temperature. In addition to the transitional elements (V,Cr,Mo,W), B was added as third element to substitute C. A systematic approach to the understanding of phases and microstructures, which form under these conditions is the purpose of this work. This includes the considerations of forming ability and thermal stability of metallic glasses. Three aspects require attention: a) absolute stability of the glass phase, b) relative stability i.e. the difference of Free Energy between the amorphous and particular crystalline phases, c) kinetic stability based on the rate and mechanisms of crystallization reactionsincluding the rate determing diffusion process. Light and electron microscopy and electron diffraction were used for the analysis of the structure of the alloys.

Type
Research Article
Copyright
Copyright © Materials Research Society 1982

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References

REFERENCES

1.Hornbogen, E. and Schmidt, I. in: Liquid and Amorphous Metals, Lüscher, E., Coufal, H. eds. (Sijthoff & Noordhoff, Alphen aan den Rijn 1980) p. 353380.Google Scholar
2.Ruhl, R. C. and Cohen, M., Trans AIME 245, 241251 (1969).Google Scholar
3.Inoue, A., Masumoto, T., Arakawa, S., Iwadachi, T., Trans JIM 19 303312 (1978).Google Scholar
4.Nowotny, H. in: Hartstoffe, Kiefer, R., Benesovsky, F. eds. (Springer, Wien 1963) p. 1344.Google Scholar
5.Goldschmidt, H. J., Interstitial Alloys, (Butterworth & Co., London 1967).10.1007/978-1-4899-5880-8Google Scholar
6.Inoue, A., Iwadachi, T., Minemura, T., Masumoto, T., Trans JIM 22, 197209 (1981).10.2320/matertrans1960.22.197Google Scholar
7.Köster, U., Herold, U. in: Glassy Metals I, Güntherodt, H. J., Beck, H. eds. (Springer, Berlin, Heidelberg, New York 1981) p. 225259.10.1007/3540104402_10Google Scholar