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The Microstructure and Properties of Layered Oxide Thin Films Fabricated by MOCVD

Published online by Cambridge University Press:  10 February 2011

Tingkai Li ,
Yongfei Zhu ,
Seshu B. Desu  and
Masaya Nagata
Seshu B. Desu
Affiliation:
Department of Materials Science and Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061
Masaya Nagata
Affiliation:
Functional Devices Laboratories, Sharp Corporation, Chiba 277, Japan
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Abstract

For the first time, layered oxide thin films of SrBi2Ta2O9 (SBT) with very good ferroelectric properties have been prepared by direct-liquid-injection MOCVD technique. The SBT films were deposited onto both Pt/Ti/SiO2/Si wafers and single-crystal sapphire substrates to measure their phase formation, microstructure and ferroelectric properties. Crystalline SBT phase had been observed at temperatures as low as 500°C. With increasing deposition temperature above 500°C, the grain size of SBT thin films was increased from 0.01 μ m to 0.2 μm. The films were found to be dense and homogenous. Typically, SBT thin films of 200 nm thick with grain size about 0. 1μm have 2Pr around 10 μC/cm2 at 5V, Ec 55.7 kV/cm, and dielectric constant around 100. The leakage 9 2 currents were as low as 8 × 10−9 A/cm2 at 150 kV/cm. The films also showed fatigue-free characteristics: no fatigue was observed up to 1.4 × 1010 switching cycles. This development of MOCVD technique for good quality SBT films make their integration into high density nonvolatile memories relatively easy.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 415: Symposium BB – Metal-Organic Chemical Vapor Deposition of Electronic Ceramics II , 1995 , 189
Copyright
Copyright © Materials Research Society 1996

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References

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