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Lifetime Prediction of Organic Coatings on Steel

Published online by Cambridge University Press:  21 February 2011

M. Kendig  and
F. Mansfeld
M. Kendig
Affiliation:
Rockwell International Science Center, 1049 Camino Dos Rios, Thousand Oaks, CA 91360
F. Mansfeld
Affiliation:
Department of Material Science, University of Southern California, Los Angeles, CA 90089–0241
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Abstract

A review of methods for predicting the lifetime of protective organic coatings on steel is presented in terms of a model which includes the steps of defect formation, transport of corrodents, loss of adhesion, and corrosion. Electrochemical impedance methods and acoustic techniques have played important roles in characterizing how the four processes interact and depend on coating processes and environmental effects. A major result of this work has been the observation that both the anodic and cathodic partial processes of the corrosion reaction limit adhesion of organic coatings on steel by generating tensile stresses and polymer degradation, thereby limiting the life of the protective system.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 125: Symposium N – Materials Stability and Environmental Degradation , 1988 , 293
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

1. Mansfeld, F. and Kendig, M., ”Lifetime Prediction of Organic Coating/Metal Systems,” Final Report for the period July 1, 1979-October 31, 1985, ONR Contract, No. N00014–79-C-0437 (1986).Google Scholar
2. Walter, G.W., Corr. Sci. 26(1), 27 (1986).Google Scholar
3. Schoff, C.K. and Pierce, P.E., ”Coating Defects: Causes and Analysis,” in Organic Coatings Science and Technology, Vol.7, Parfitt, G. and Patsis, A., eds., Marcel Dekker, 1984.Google Scholar
4. Kendig, M., Mansfeld, F. and Arora, A., ”Evaluation of Protective Coatings with Acoustic Emission and Impedance Measurements,” 9th Int. Congr. on Metallic Corrosion, Toronto, Canada (1984), Vol. 4–73.Google Scholar
5. Kendig, M.W., Allen, A.T., Jeanjaquet, S.L. and Mansfeld, F., ”The Application of Impedance Spectroscopy to the Evaluation of Corrosion Protection by Inhibitors and Polymer Coatings,” Electrochemical Techniques for Corrosion Engineering, Baboian, R., Ed.; NACE, Houston, TX (1986).Google Scholar
6. Kendig, M., Tsai, S. and Mansfeld, F., Materials Performance 23, 37 (1984).Google Scholar
7. Kendig, M., Addison, R. and Jeanjaquet, S., ”Environmental Integrity of the Coating/Metal Interface,” Annual Report, ONR Contract No. N00014–87-C-0075 (1988).Google Scholar
8. Kendig, M., Addison, R. and Jeanjaquet, S., ”Acoustic Microscopy of the Cathodic Disbonding of Steel,” in preparation.Google Scholar
9. Addison, R. and Kendig, M., ”In Situ Measurement of Cathodic Disbonding of Polybutadiene Coatings on Steel,” 17th International Symposium on Acoustical Imaging, Sendai, Japan, June 1988.Google Scholar
10. Mansfeld, F. and Kendig, M., ”Electrochemical Impedance Tests for Protective Coatings,” ASTM STP 866, p. 122 (1985).Google Scholar
11. Dickie, R.A., Hammond, J.S. and Holubka, J.W., Ind. Eng. Chem. Prod. Res. Dev. 20, 339 (1981).CrossRefGoogle Scholar
12. Ritter, J., J. Coat. Tech. 54(695), 51 (1982).Google Scholar
13. Castle, J. and Watts, J., I&D 24, 361 (1985).Google Scholar
14. Koehler, E., Corrosion 40(1), 5 (1984).Google Scholar
15. Mansfeld, F., Kendig, M. and Tsai, S., ”Evaluation of Organic Coating/Metal Systems by AC Impedance Techniques,” Proc. 8th Int. Congress on Metallic Corrosion, Mainz, West Germany (1981), p. 1014.Google Scholar
16. Mansfeld, F., Lumsden, J.B., Jeanjaquet, S.L. and Tsai, S., ”Evaluation of Surface Pretreatment Methods for Application of Organic Coatings,” Corrosion Control by Organic Coatings, Leidheiser, H., ed., NACE (1980), p. 355.Google Scholar
17. Mansfeld, F., Kendig, M.W. and Tsai, S., Corrosion 38, 478 (1982).Google Scholar
18. Kendig, M., Jeanjaquet, S., White, J. and Mansfeld, F., ”Electrochemical Impedance Evaluation of the Role of Corrosion Inhibiting Pigments in Organic Coatings in Corrosion Protection by Organic Coatins, Electrochemical Society Proceedings, Vol.87– 2, Kendig, M. and Keidheiser, H., eds. (1987).Google Scholar
19. Isaacs, H. and Kendig, M., Corrosion 36(6), 269 (1980).Google Scholar
20. Standish, J. and Leidheiser, H. Jr.,, Corrosion 36(8), 390 (1980).Google Scholar
21. Bacon, R.C., Smith, J.J. and Rugg, F.M., Ind. Chem. 40, 161 (1948).Google Scholar
22. Mayne, J.E.D. and Mills, D.J., Oil and Colour Chemists Assoc. J. 58, 155 (1975).Google Scholar
23. Brasher, D. and Kingsbury, , J. Appl. Chem. 4, 62 (1954).Google Scholar
24. Brasher, D. and Nurse, T.J., J. App. Chem. 9, 96 (1959).Google Scholar
25. Touhsaent, R. and Leidheiser, H., Corrosion 28, 435 (1972).Google Scholar
26. Menges, G. and Schneider, W., Kunststofftechnik 12(11), 316 (1973).Google Scholar
27. Kendig, M. and Leidheiser, H., J. Electrochem. Soc. 123, 982 (1976).Google Scholar
28. Beaunier, L., Epelboin, I., Lestrade, J.C., Takenouti, H., Surf. Technol. 4(3), 237 (1976).Google Scholar
29. Mansfeld, F. and Kendig, M.W., Werkstoffe und Korrosion 36, 473 (1985).Google Scholar
30. Rugeri, T. and Beck, T., ”Application of Electrochemical Engineering Methods and Theory to Solving Corrosion and Adhesion Problems with Organic Coatings,” Interim Summary, Contract No. N62299–82-C-0281, Naval Air Development Center, Warminster, PA, Report No. NADC-84107–60 (1984), and references therein.Google Scholar
31. Mansfeld, F., Jeanjaquet, S.L. and Kendig, M.W., ”An Electrochemical Impedance Spectroscopy Study of Reactions at the Metal/Coating Interface,” Corr. Sci. 26(9), 735 (1986).Google Scholar
32. Hansmann, H., Ind. Eng. Chem. Prod. R&D, 24, 252 (1985).Google Scholar
33. Balera, M.S., Strivens, T.A. and Williams-Wynn, D.E.A., J. Oil and Colour Chemists Assoc. (5), 133 (1984).Google Scholar
34. Balera, M.S., Strivens, T.A. and Williams-Wynn, D.E.A., J. Oil and Colour Chemists Assoc., 143 (1984).Google Scholar
35. Hansmann, H., Moslé, H.G., Adhesion 28, 18–21 and 24–26 (1982).Google Scholar
36. Rooun, J.S. and Rawlings, R.D., J. Mater. Sci. 17, 1745 (1982).CrossRefGoogle Scholar
37. Moslé, H.G., Wellenköter, B., Z. Werkstofftech. 9, 265 (1978).Google Scholar
38. Tsuru, T., Sagara, A. and Haruyawa, S., Corrosion 43(11), 703 (1987).Google Scholar
39. Thornton, J.S., Montgomery, R.E. and Cartier, J.F., ”Failure Rate Model for Cathodic Delamination of Protective Coatings,” NRL Memorandum Report No. 5484, May 30, 1985.Google Scholar