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Influence of Iron(II) and Iron(III) Ions on the Corrosion of MTR Fuel Element Claddings in Repository-Relevant Brines
Published online by Cambridge University Press: 10 February 2011
Abstract
After the USA decided in 1988 to no longer accept spent fuel elements from German material test reactors (MTR), a national back-end fuel cycle alternative was sought in the Federal Republic of Germany [1]. The aim is their direct final disposal in deep, stable geologic formations. The corrosion of material test reactor (MTR)-fuel element claddings (aluminium) in repository-relevant brines was examined. Before the aluminium cladding material can corrode, the POLLUX cask, containing the fuel elements, must be corroded. In this case, iron(II) and iron(III) ions are present in the brine. These ions decisively influence the corrosion of the MTR fuel element cladding material, therefore the mechanism responsible for this phenomenon should be identified. Tests were performed in which Fe(II) and Fe(III) salts were added to the brines. In these experiments, the percentage mass decrease of the aluminium cladding, the iron content of the brine, as well as the pH value were determined. As expected the results provided the information about the corrosion mechanism. The higher the concentration of iron ions in the brines, the higher the aluminium corrosion rate was for all three brines. Identical redox equilibria between Fe(II) and Fe(III) were formed in the brine, irrespective of whether Fe(II) or Fe(III) salt had been added. It is assumed that the acceleration of the corrosion rate is based on the fact that Fe(II) is reduced to metallic iron by absorbing the electrons produced during the oxidation of aluminium to Al(III). The aluminium cladding material does not function as a barrier for the release of radionuclides from the fuel elements. The results of this study show that the 0.38 mm thick aluminium cladding will corrode through after approximately four weeks.
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- Copyright © Materials Research Society 1998