Published online by Cambridge University Press: 01 February 2011
Thin metal films deposited on elastomeric substrates can remain electrically conducting at tensile strains up to ~∼00%. We recently used finite-element simulation to explore the rupture process of a metal film on an elastomer. The simulation predicted the highest stretchability on stiff elastomeric substrates [1]. We now report experiments designed to verify this prediction. A ∼15-μm thick silicone elastomer layer with Young's modulus E ∼ 160 MPa is deposited on a 1mm thick membrane of polydimethylsiloxane (PDMS), a silicone elastomer with E ∼3 MPa. Metal stripes consisting of 25-nm thick gold (Au) film sandwiched between two 5-nm thick chromium (Cr) adhesion layers are fabricated either on top of the stiff layer spun onto the soft membrane substrate, or are encapsulated at the interface between the two elastomers. Encapsulated gold films remain electrically conducting beyond 40% strain. But conductors deposited on top of stiff elastomer lose conduction at strains of 3-8%. These results suggest that, in addition to the stiffness of the elastomeric substrate, the initial microstructure of the metal film plays a role in determining its stretchability.