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High Pressure Synthesis of RuSr2MeCu2O8 (Me = Ho or Y)

Published online by Cambridge University Press:  18 March 2011

R. Ruiz-Bustos
Affiliation:
Laboratorio Complutense de Altas Presiones and Departmento de Química Inorgánica. Facultad de Ciencias Químicas., Universidad Complutense., 28040., Madrid., Spain., EU
J. M. Gallardo-Amores
Affiliation:
Laboratorio Complutense de Altas Presiones and Departmento de Química Inorgánica. Facultad de Ciencias Químicas., Universidad Complutense., 28040., Madrid., Spain., EU
E. Morán
Affiliation:
Laboratorio Complutense de Altas Presiones and Departmento de Química Inorgánica. Facultad de Ciencias Químicas., Universidad Complutense., 28040., Madrid., Spain., EU
J. P. Attfield
Affiliation:
Interdisciplinary Research Centre in Superconductivity. Madingley Road. Cambridge CB3 OHE and Department of Chemistry., University of Cambridge., Lensfield Road. Cambridge CB2 1EW., United Kingdom., EU
R. Sáez-Puche
Affiliation:
Laboratorio Complutense de Altas Presiones and Departmento de Química Inorgánica. Facultad de Ciencias Químicas., Universidad Complutense., 28040., Madrid., Spain., EU
M. A. Alario-Franco
Affiliation:
Laboratorio Complutense de Altas Presiones and Departmento de Química Inorgánica. Facultad de Ciencias Químicas., Universidad Complutense., 28040., Madrid., Spain., EU
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Abstract

The synthesis at high pressures ( ∼60 Kbar) and high temperatures (∼1100 °C) of the title new ruthenates has been achieved and the materials compared to the gadolinium analogue. The structure remains tetragonal (S.G. P4/mmm) and the cell parameters linearly decrease following the lanthanide contraction. Preliminary results concerning the complex magnetic properties of these materials, where superconductivity, antiferromagnetism and a superimposed ferromagnetic ordering coexist, are presented.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

1. Alario-Franco, M. A., Morán, E., Sáez-Puche, R., García-Alvarado, F., Amador, U., Barahona, M., Fernández, F., Pérez-Frías, M. T. and Vicent, J. L.. Mat. Res. Bull., 23, 313 (1988).Google Scholar
2. Alario-Franco, M.A., Chaillout, C., Capponi, J. J., Tholence, J. L. and Souletie, B.. Physica C, 222, 52, (1994).Google Scholar
3. Takayama-Muromachi, E.. Chem. Mater., 10, 2686 (1998).Google Scholar
4. McMillan, P. F.. Current Opinion in Solid State and Materials Science, 4, 171 (1999).Google Scholar
5. Hiroi, Z. and Takano, M.. Physica C., 235–240, 29 (1994).Google Scholar
6. McLaughlin, A., Zhou, W., Attfield, J. P., Fitch, A. N. and Tallon, J. L.. Phys. Rev. B, 60(10), 7512. (1999).Google Scholar
7. Bauernfein, L., Widder, W. and Braun, H.D.. Physica C, 254, 151 (1995).Google Scholar
8. Tallon, J. L.. Bernhard, C., Bowden, M. E., Giilberd, P. W., Soto, T. M. and Pringle, D. J..Google Scholar
9. IEEE Trans. Appl. Supercond. 9, 1696, (1999).Google Scholar
10. Felner, I., Asaf, U., Reich, S. and Tsabba, Y.. Physica C., 311, 163, (1999).Google Scholar
11. Bernhard, C., Tallon, J. L., Niedermayer, Ch., Blasius, Th., Golnik, A., Brücher, E., Kremer, R. K., Noakes, D. R., Stronach, C. E. and Ansaldo, E. J.. Phys. Rev. B, 59(21), 14099.Google Scholar
12. Chmaissem, O., Jorgensen, J. D., Shaked, H., Dollar, P. and Tallon, J. L.. Phys. Rev. B, 61(9), 6401. (2000).Google Scholar
13. Williams, G. V. M. and Krémer, S.. Phys. Rev. B., 62(6), 4132 (2000).Google Scholar
14. Nakamura, K., Park, K.T., Freeman, A. J. and Jorgensen, J.D.. Phys. Rev. B., 63, 024507 (2000).Google Scholar
15. Jorgensen, J.D., Chmaissem, O., Shaked, H., Short, S., Klamut, P. W., Dabrowski, B. and Tallon, J. L.. Phys. Rev. B (submitted).Google Scholar
16. Shannon, R.D. and Prewitt, C.. Acta Cryst., B–25, 925 (1969).Google Scholar
17. Lynn, J. W., Keimer, B., Ulrich, C., Bernhard, C. and Tallon, J. L.. Phys. Rev.B., 61 (22), R14964 (2000).Google Scholar