Hostname: page-component-745bb68f8f-5r2nc Total loading time: 0 Render date: 2025-02-09T22:10:10.663Z Has data issue: false hasContentIssue false
  • English
  • Français

High Pressure Synchrotron Diffraction of KCa2Nb3O10, a Layered Perovskite Compound

Published online by Cambridge University Press:  10 February 2011

K. A. Steiner  and
W. T. Petuskey
K. A. Steiner
Affiliation:
Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ, 85287
W. T. Petuskey
Affiliation:
Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ, 85287
Get access

Abstract

High pressure synchrotron x-ray diffraction experiments were conducted on KCa2Nb3O10, to determine lattice constants as a function of pressure. A diamond anvil cell was used to produce pressures up to 66 GPa. A phase transition occurred at 13.5 GPa. From the lattice constants, linear compressibilities of 8.55 × 10-4 GPa-1 in the a direction, -9.40 × 10-4 GPa-1 in the b direction, and 142 × 10-4 GPa-1 in the c direction, and a bulk modulus of 68.5 GPa were found for the lower pressure orthorhombic phase.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 524: Symposium V – Application of Synchrotron Radiation Techniques…IV , 1998 , 133
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Jacobson, A. in Chemical Physics of Intercalation II, edited by Bernier, P., et al., Plenum Press, New York, 1993, p. 117–139.Google Scholar
2. Dion, M., Ganne, M. and Tournoux, M., Mat. Res. Bull. 16, p. 1429(1981).Google Scholar
3. Sambasivan, S. (private communication).Google Scholar
4. Heinz, D. L. and Jeanloz, R., J. Appl. Phys. 55, 885 (1984).Google Scholar
5. Finger, L. W. in Modern Powder Diffraction, edited by Bish, D. L. and Post, J. E. , Mineralogical Society of America, Washington, D. C., 1989, p. 309–331.Google Scholar
6. Swanson, and Tatge, , Natl. Bur. Stand., Circ. 539, I33 (1953).Google Scholar
7. Larson, A. C. and Von Dreele, R. B.. GSAS-Generalized Crystal Structure Analysis System, Los Alamos National Laboratory Report No. LA-UR-86-748 (1987).Google Scholar
8. Fei, Y., and Mao, H. K., J. Geophys. Res. 98, p. 875(1993).Google Scholar
9. Xia, X., Weidner, D. J., and Zhao, H., American Mineralogist, 83, p. 68 (1998).Google Scholar
10. Zhao, Y. X. and Spain, I. L., Physical Review B 40, p. 993 (1989).Google Scholar
11. Jehng, Jih-Mirn and Wachs, Israel E., Chem. Mater., 3, p. 100 (1991).Google Scholar