Hostname: page-component-78c5997874-t5tsf Total loading time: 0 Render date: 2024-11-02T23:28:30.818Z Has data issue: false hasContentIssue false
  • English
  • Français

The Generation of a Carbon Nanotube- Cyclodextrin Complex

Published online by Cambridge University Press:  15 March 2011

G.F. Farrell ,
G. Chambers ,
A.B Dalton ,
E. Cummins ,
M. McNamara ,
R.H. Baughman ,
M. in het Panhuis  and
H.J. Byrne
G.F. Farrell
Affiliation:
Facility for Optical Characterisation And Spectroscopy (FOCAS), DIT, Kevin Street, Dublin 08, Ireland
G. Chambers
Affiliation:
Facility for Optical Characterisation And Spectroscopy (FOCAS), DIT, Kevin Street, Dublin 08, Ireland Trinity College Dublin, Dublin 02, Ireland/ Media Lab Europe, Sugar House Lane, Bellevue, Dublin 08, Ireland
A.B Dalton
Affiliation:
UTD NanoTech Institute University of Texas at Dallas Richardson 75080, USA
E. Cummins
Affiliation:
Facility for Optical Characterisation And Spectroscopy (FOCAS), DIT, Kevin Street, Dublin 08, Ireland
M. McNamara
Affiliation:
Facility for Optical Characterisation And Spectroscopy (FOCAS), DIT, Kevin Street, Dublin 08, Ireland
R.H. Baughman
Affiliation:
UTD NanoTech Institute University of Texas at Dallas Richardson 75080, USA
M. in het Panhuis
Affiliation:
Trinity College Dublin, Dublin 02, Ireland/ Media Lab Europe, Sugar House Lane, Bellevue, Dublin 08, Ireland
H.J. Byrne
Affiliation:
Facility for Optical Characterisation And Spectroscopy (FOCAS), DIT, Kevin Street, Dublin 08, Ireland
Get access

Abstract

In this study the intermolecular interactions of small diameter (∼0.7nm) carbon nanotubes and γ-cyclodextrin were examined. Four samples of γ cyclodextrin and HiPco carbon nanotubes were prepared. The first, by grinding the tubes and the cyclodextrin (1:30 ratio) together in a dry mixture, the second was prepared in a similar fashion but was ground in the presence of water (1ml). Finally an aqueous solution of γ-cyclodextrin (0.3M) and HiPco carbon nanotubes (5mg) was prepared by refluxing for ∼100 hours, forming a pale yellow solution from which a number of crystals were produced, both the solution and the recrystallised material were analysed. The samples were analysed using UV-Vis-NIR and Raman spectroscopy. The results presented are the first spectroscopic evidence of an intermolecular interaction between γ-cyclodextrin and single wall nanotubes.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 703: Symposia U/V – Nanophase and Nanocomposite Materials IV , 2001 , V13.8
Copyright
Copyright © Materials Research Society 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Iijima, S., Ichihashi, T., Nature 363, 603, (1993).Google Scholar
[2] Rao, C. N. R., Satishkumar, B. C., Govindaraj, A., Nath, M. Chemphyschem 2, 78, (2001)Google Scholar
[3] Curran, S., Ajayan, P.M.. Blua, W. Carroll, D., Coleman, J.N., Dalton, A.B. Davey, A., Dury, A., McCarthy, B., Maier, S.. Adv. Mat. 10, 1091 (1998)Google Scholar
[4] Duesberg, G.S., Blau, W., Byrne, H.J., Muster, J., Burghard, M., Roth, S. Synth. Met. 103, 2484 (1999)Google Scholar
[5] Nikolaev, P., Bronikowski, M.J., Bradely, R.K., Rohmund, F., Colbert, D.T., Smith, K. A., Smalley, R.E., Chem. Phys. Lett., 313, 91(1999)Google Scholar
[6] Chiang, I. W., Brinson, B. E., Huang, A. Y., Willis, P. A., Bronikowski, M. J., Margrave, J. L., Smalley, R. E., and Hauge, R. H. J. Phys. Chem. B 105, 8297, (2001)Google Scholar
[7] Chen, J., Dyer, M. J., and Yu, M-F. J. Am. Chem. Soc., 123, 6201 (2001)Google Scholar
[8] Yudasaka, M., Kataura, H., Ichihashi, T., Qin, L.-C., Kar, S., and Iijima, S. Nano Letters 1, 487 (2001)Google Scholar
[9] Szejtli, J. Chem. Rev., 98, 1743 (1998)Google Scholar
[10] Samal, S. and Geckeler, K. E., Chem. Commun., 1101, (2000)Google Scholar
[11] Kataura, H., Kumazawa, Y., Maniwa, Y.. Umezu, I., Suzki, S., Ohtsuka, Y. and Achiba, Y.. Synth. Met. 103, 2555 (1999)Google Scholar
[12] Hadjiev, V. G., Iliev, M. N., Arepalli, S. Files, P.B. S. App. Phys. Letts. 78, 3193 (2001)Google Scholar
[13] Venkateswaran, U. D., Rao, A. M., Richter, E, Menon, M., Rinzler, A., Smalley, R. E. Eklund, P. C.. App. Phys. Letts. 59, 10928 (1999)Google Scholar